2-Benzoyl-4-phenyl-1,2,5-thiadiazol-3(2<i>H</i>)-one 1,1-Dioxide

3,5-Diphenyl-4<i>H</i>-1,2,6-thiadiazin-4-one treated with <i>meta</i>-chloroperoxybenzoic acid undergoes an oxidative ring contraction to give 2-benzoyl-4-phenyl-1,2,5-thiadiazol-3(2<i>H</i>)-one 1,1-dioxide in a 29% yield, the structure of which is supported by...

وصف كامل

التفاصيل البيبلوغرافية
الحاوية / القاعدة:Molbank
المؤلفون الرئيسيون: Emmanouil Broumidis, Samuel B. H. Patterson, Georgina M. Rosair, Panayiotis A. Koutentis, Andreas S. Kalogirou
التنسيق: مقال
اللغة:الإنجليزية
منشور في: MDPI AG 2024-02-01
الموضوعات:
heterocycle
thiadiazine
thiadiazole
ring contraction
sulfone
oxidation
الوصول للمادة أونلاين:https://www.mdpi.com/1422-8599/2024/1/M1774
الوصف
الملخص:3,5-Diphenyl-4<i>H</i>-1,2,6-thiadiazin-4-one treated with <i>meta</i>-chloroperoxybenzoic acid undergoes an oxidative ring contraction to give 2-benzoyl-4-phenyl-1,2,5-thiadiazol-3(2<i>H</i>)-one 1,1-dioxide in a 29% yield, the structure of which is supported by single-crystal X-ray diffraction analysis and the available spectroscopic data.
تدمد:1422-8599

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