Ionic Liquids as Solvents for Rhodium and Platinum Catalysts Used in Hydrosilylation Reaction
A group of imidazolium and pyridinium based ionic liquids has been synthetized, and their ability to dissolve and activate the catalysts used in hydrosilylation reaction of 1-octane and 1,1,1,3,5,5,5-heptamethyltrisiloxane was investigated. An organometallic catalyst as well as inorganic complexes o...
| Published in: | Molecules |
|---|---|
| Main Authors: | Witold Zielinski, Rafal Kukawka, Hieronim Maciejewski, Marcin Smiglak |
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2016-08-01
|
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/21/9/1115 |
Similar Items
Hydrosilylation of Aldehydes by a Manganese α-Diimine Complex
by: Veeranna Yempally, et al.
Published: (2020-11-01)
by: Veeranna Yempally, et al.
Published: (2020-11-01)
bis-Nitrile and bis-Dialkylcyanamide Platinum(II) Complexes as Efficient Catalysts for Hydrosilylation Cross-Linking of Siloxane Polymers
by: Regina M. Islamova, et al.
Published: (2016-03-01)
by: Regina M. Islamova, et al.
Published: (2016-03-01)
Formal Anti‐Markovnikov Addition of Water to Olefins by Titanocene‐Catalyzed Epoxide Hydrosilylation: From Stoichiometric to Sustainable Catalytic Reactions
by: Sebastian Höthker, et al.
Published: (2023-07-01)
by: Sebastian Höthker, et al.
Published: (2023-07-01)
Copper(I) Complexes of Mesoionic Carbene: Structural Characterization and Catalytic Hydrosilylation Reactions
by: Stephan Hohloch, et al.
Published: (2015-04-01)
by: Stephan Hohloch, et al.
Published: (2015-04-01)
Tying Covalent Organic Frameworks through Alkene Metathesis and Supported Platinum as Efficient Catalysts for Hydrosilylation
by: Defa Gu, et al.
Published: (2022-01-01)
by: Defa Gu, et al.
Published: (2022-01-01)
Hydrosilylation Reactions Catalyzed by Rhenium
by: Duo Wei, et al.
Published: (2021-04-01)
by: Duo Wei, et al.
Published: (2021-04-01)
First application of chiral phosphotriesters in asymmetric metal catalysis: enantioselective Zn-catalyzed hydrosilylation of ketones in the presence of BINOL-derived phosphates
by: Ngo Ndimba, Alphonsine, et al.
Published: (2021-03-01)
by: Ngo Ndimba, Alphonsine, et al.
Published: (2021-03-01)
Pd/S cooperativity: from stoichiometric activation of Si−H bonds to catalytic hydrosilylation
by: Arnaud Clerc, et al.
Published: (2025-01-01)
by: Arnaud Clerc, et al.
Published: (2025-01-01)
1946 and the Early History of Hydrosilylation
by: Kenrick M. Lewis, et al.
Published: (2022-07-01)
by: Kenrick M. Lewis, et al.
Published: (2022-07-01)
Short-Chained Platinum Complex Catalyzed Hydrosilylation under Thermomorphic Conditions: Heterogeneous Phase Separation at Ice Temperature
by: Chiao-Fan Chiu, et al.
Published: (2021-01-01)
by: Chiao-Fan Chiu, et al.
Published: (2021-01-01)
Concise methods for the synthesis of chiral polyoxazolines and their application in asymmetric hydrosilylation
by: Wei Jie Li, et al.
Published: (2010-03-01)
by: Wei Jie Li, et al.
Published: (2010-03-01)
Sweet, Sugar-Coated Hierarchical Platinum Nanostructures for Easy Support, Heterogenization and Separation
by: Dennis Woitassek, et al.
Published: (2022-09-01)
by: Dennis Woitassek, et al.
Published: (2022-09-01)
Construction of Pt-Cu-Vinylamine Complex on Hazelnut Shell Biochar as a Catalyst Used for Hydrosilylation of Alkenes by Tertiary Silanes
by: Jing Zhou, et al.
Published: (2025-09-01)
by: Jing Zhou, et al.
Published: (2025-09-01)
New hybrid materials based on poly(ethyleneoxide)-grafted polysilazane by hydrosilylation and their anti-fouling activities
by: Thi Dieu Hang Nguyen, et al.
Published: (2013-10-01)
by: Thi Dieu Hang Nguyen, et al.
Published: (2013-10-01)
Response of Photoluminescence of H-Terminated and Hydrosilylated Porous Si Powders to Rinsing and Temperature
by: Kurt W. Kolasinski, et al.
Published: (2020-08-01)
by: Kurt W. Kolasinski, et al.
Published: (2020-08-01)
Molybdenum-Catalyzed (<i>E</i>)-Selective Anti-Markovnikov Hydrosilylation of Alkynes
by: Feihua Ye, et al.
Published: (2024-12-01)
by: Feihua Ye, et al.
Published: (2024-12-01)
Mesoscale Modeling of Phase Separation Controlled by Hydrosilylation in Polyhydromethylsiloxane (PHMS)-Containing Blends
by: Yao Xiong, et al.
Published: (2022-09-01)
by: Yao Xiong, et al.
Published: (2022-09-01)
Preparation of T8 and double-decker silsesquioxane-based Janus-type molecules: molecular modeling and DFT insights
by: Julia Duszczak-Kaczmarek, et al.
Published: (2024-08-01)
by: Julia Duszczak-Kaczmarek, et al.
Published: (2024-08-01)
Thermoregulated biphasic ionic liquids: Effective catalysts in aldehydic–amide condensation reaction
by: Hua Qian, et al.
Published: (2017-11-01)
by: Hua Qian, et al.
Published: (2017-11-01)
Alkaline ionic liquids applied in supported ionic liquid catalyst for selective hydrogenation of citral to citronellal
by: Eero eSalminen, et al.
Published: (2014-02-01)
by: Eero eSalminen, et al.
Published: (2014-02-01)
NO Dissociation on Platinum and Platinum-Rhodium Alloy: A Theoretical Investigation
by: Khanh Bao Vu, et al.
Published: (2024-04-01)
by: Khanh Bao Vu, et al.
Published: (2024-04-01)
Tunable Aryl Alkyl Ionic Liquid Supported Synthesis of Platinum Nanoparticles and Their Catalytic Activity in the Hydrogen Evolution Reaction and in Hydrosilylation
by: Dennis Woitassek, et al.
Published: (2023-01-01)
by: Dennis Woitassek, et al.
Published: (2023-01-01)
Transition-Metal-Catalyzed Asymmetric Reduction of 2-Pyridine Ketones
by: Vidhul Vasudevan, et al.
Published: (2024-12-01)
by: Vidhul Vasudevan, et al.
Published: (2024-12-01)
Selective Double Addition Reaction of an E‒H Bond (E = Si, B) to a C≡N Triple Bond of Organonitriles
by: Masumi Itazaki, et al.
Published: (2018-10-01)
by: Masumi Itazaki, et al.
Published: (2018-10-01)
Silica-Based Supported Ionic Liquid-like Phases as Heterogeneous Catalysts
by: Anna Wolny, et al.
Published: (2022-09-01)
by: Anna Wolny, et al.
Published: (2022-09-01)
Mutual Placement of Isocyanide and Phosphine Ligands in Platinum(II) Complexes [PtHal<sub>2</sub>L<sup>1</sup>L<sup>2</sup>] (Hal = Cl, Br, I; L<sup>1</sup>,L<sup>2</sup> = CNCy, PPh<sub>3</sub>) Leads to Highly-Efficient Photocatalysts for Hydrosilylation of Alkynes
by: Maria V. Kashina, et al.
Published: (2023-11-01)
by: Maria V. Kashina, et al.
Published: (2023-11-01)
Catalytic Reduction of Acetophenone Promoted with Quinuclidinol-Based Quaternary Ammonium Ionic Liquid as a Sustainable Solvent
by: Gaojin Zhou, et al.
Published: (2023-11-01)
by: Gaojin Zhou, et al.
Published: (2023-11-01)
Synthesis and utility of N-boryl and N-silyl enamines derived from the hydroboration and hydrosilylation of N-heteroarenes and N-conjugated compounds
by: Vinh Do Cao, et al.
Published: (2024-06-01)
by: Vinh Do Cao, et al.
Published: (2024-06-01)
Ionic Liquids for Development of Heterogeneous Catalysts Based on Nanomaterials for Biocatalysis
by: Anna Wolny, et al.
Published: (2021-08-01)
by: Anna Wolny, et al.
Published: (2021-08-01)
Biphasic Chemistry Utilising Ionic Liquids
by: Paul J. Dyson
Published: (2005-03-01)
by: Paul J. Dyson
Published: (2005-03-01)
Tailoring the Surface Enrichment of a Pt Catalyst in Ionic Liquid Solutions by Choice of the Solvent
by: Daniel Hemmeter, et al.
Published: (2024-05-01)
by: Daniel Hemmeter, et al.
Published: (2024-05-01)
Polystyrene-supported pyridinium chloroaluminate ionic liquid as a new heterogeneous Lewis acid catalyst for selective synthesis of benzimidazoles
by: Parvanak Boroujeni Kaveh, et al.
Published: (2013-01-01)
by: Parvanak Boroujeni Kaveh, et al.
Published: (2013-01-01)
Ionic quaternary ammonium-triazole polymers as efficient single-component catalysts for CO2 conversion
by: Pobporn Promchan, et al.
Published: (2024-12-01)
by: Pobporn Promchan, et al.
Published: (2024-12-01)
Mechanistic insights on ionic liquid and poly(ionic liquid) solutions for CO2 capture and cycloaddition reactions
by: Raquel V. Barrulas, et al.
Published: (2025-06-01)
by: Raquel V. Barrulas, et al.
Published: (2025-06-01)
Design and Characterization of Epoxy Resin Systems Based on Mixtures of Imidazolium-Based Ionic Liquids with Docusate and Dicyanamide Anions
by: Andrea Szpecht, et al.
Published: (2024-09-01)
by: Andrea Szpecht, et al.
Published: (2024-09-01)
Thermal and Electrochemical Properties of Ionic Liquids Bearing Allyl Group with Sulfonate-Based Anions—Application Potential in Epoxy Resin Curing Process
by: Andrea Szpecht, et al.
Published: (2023-01-01)
by: Andrea Szpecht, et al.
Published: (2023-01-01)
The Choice of Rhodium Catalysts in [2+2+2] Cycloaddition Reaction: A Personal Account
by: Anna Pla-Quintana, et al.
Published: (2022-02-01)
by: Anna Pla-Quintana, et al.
Published: (2022-02-01)
Design and Synthesis of New Sulfonic Acid Functionalized Ionic Liquids as Catalysts for Esterification of Fatty Acids with Bioethanol
by: Thu Huong Nguyen Thi, et al.
Published: (2023-07-01)
by: Thu Huong Nguyen Thi, et al.
Published: (2023-07-01)
Sn-MCM-41 as Efficient Catalyst for the Conversion of Glucose into 5-Hydroxymethylfurfural in Ionic Liquids
by: Qing Xu, et al.
Published: (2013-11-01)
by: Qing Xu, et al.
Published: (2013-11-01)
Preparation of Comb-Shaped Polyether with PDMS and PEG Side Chains and Its Application in Polymer Electrolytes
by: Tomoya Enoki, et al.
Published: (2025-07-01)
by: Tomoya Enoki, et al.
Published: (2025-07-01)
Similar Items
-
Hydrosilylation of Aldehydes by a Manganese α-Diimine Complex
by: Veeranna Yempally, et al.
Published: (2020-11-01) -
bis-Nitrile and bis-Dialkylcyanamide Platinum(II) Complexes as Efficient Catalysts for Hydrosilylation Cross-Linking of Siloxane Polymers
by: Regina M. Islamova, et al.
Published: (2016-03-01) -
Formal Anti‐Markovnikov Addition of Water to Olefins by Titanocene‐Catalyzed Epoxide Hydrosilylation: From Stoichiometric to Sustainable Catalytic Reactions
by: Sebastian Höthker, et al.
Published: (2023-07-01) -
Copper(I) Complexes of Mesoionic Carbene: Structural Characterization and Catalytic Hydrosilylation Reactions
by: Stephan Hohloch, et al.
Published: (2015-04-01) -
Tying Covalent Organic Frameworks through Alkene Metathesis and Supported Platinum as Efficient Catalysts for Hydrosilylation
by: Defa Gu, et al.
Published: (2022-01-01)
