When transition-metal-catalyzed C–H activation meets allene chemistry

Transition-metal-catalyzed allenes-involved C–H functionalizations demonstrate unique selectivity and undergo exceptional pathways due to the existence of elusive orthogonal cumulative CCC bonds. As a result, it allows for a diverse array of C–H activation reactions, such as allylation, alkenylati...

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Bibliographic Details
Published in:Tetrahedron Chem
Main Authors: Shu-Meng Deng, Yu-Xuan Zhao, Chengming Wang
Format: Article
Language:English
Published: Elsevier 2023-12-01
Subjects:
Transition metal
Allene
C–H activation
Annulation
Regioselectivity
Online Access:http://www.sciencedirect.com/science/article/pii/S2666951X23000153
Description
Summary:Transition-metal-catalyzed allenes-involved C–H functionalizations demonstrate unique selectivity and undergo exceptional pathways due to the existence of elusive orthogonal cumulative CCC bonds. As a result, it allows for a diverse array of C–H activation reactions, such as allylation, alkenylation, allenylation, dienylation, propargylation, and annulation. In this review, we comprehensively summarize the noteworthy aspects of transition-metal-catalyzed C–H functionalizations involving variously substituted allenes.
ISSN:2666-951X

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