| 總結: | Lithium-sulfur batteries with high theoretical energy density and cheap cost can meet people’s need for efficient energy storage, and have become a focus of the research on lithium-ion batteries. However, owing to their poor conductivity and “shuttle effect”, lithium-sulfur batteries are difficult to commercialize. In order to solve this problem, herein a polyhedral hollow structure of cobalt selenide (CoSe<sub>2</sub>) was synthesized by a simple one-step carbonization and selenization method using metal-organic bone MOFs (ZIF-67) as template and precursor. CoSe<sub>2</sub> is coated with conductive polymer polypyrrole (PPy) to settle the matter of poor electroconductibility of the composite and limit the outflow of polysulfide compounds. The prepared CoSe<sub>2</sub>@PPy-S composite cathode shows reversible capacities of 341 mAh g<sup>−1</sup> at 3 C, and good cycle stability with a small capacity attenuation rate of 0.072% per cycle. The structure of CoSe<sub>2</sub> can have certain adsorption and conversion effects on polysulfide compounds, increase the conductivity after coating PPy, and further enhance the electrochemical property of lithium-sulfur cathode material.
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