Lone pair expression in fluorinated two-dimensional hybrid perovskite enables multiaxial ferroelectricity and nonlinear optical response
Abstract Two-dimensional (2D) hybrid organic-inorganic perovskites (HOIPs) with tunable octahedra are promising for flexible devices due to spontaneous-polarization-driven functionalities like ferroelectric memory, piezoelectric sensing and optical switches. However, achieving large spontaneous pola...
| Published in: | Nature Communications |
|---|---|
| Main Authors: | Hao-Fei Ni, Qi-Fang Zhou, Jia-Qi Luo, Gele Teri, Lei Pan, Lou-Kai Ye, Qiang-Qiang Jia, Pei-Zhi Huang, Pei-Guo Liu, Chang-Feng Wang, Zhi-Xu Zhang, Da-Wei Fu, Yi Zhang |
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2025-08-01
|
| Online Access: | https://doi.org/10.1038/s41467-025-63134-6 |
Similar Items
Mechanically deformable organic ferroelectric crystal with plasticity optimized by fluorination
by: Pei-Zhi Huang, et al.
Published: (2025-03-01)
by: Pei-Zhi Huang, et al.
Published: (2025-03-01)
Lone-pair activated ferroelectricity and stable charged domain wall in Bi monolayer
by: Shulin Zhong, et al.
Published: (2024-09-01)
by: Shulin Zhong, et al.
Published: (2024-09-01)
Methylhydrazine Lone‐Pair Engineering for Polar Lead‐Free Perovskite Enables Self‐Powered X‐Ray Detection
by: Ruiqing Li, et al.
Published: (2025-05-01)
by: Ruiqing Li, et al.
Published: (2025-05-01)
Disentangling the effects of structure and lone-pair electrons in the lattice dynamics of halide perovskites
by: Sebastián Caicedo-Dávila, et al.
Published: (2024-05-01)
by: Sebastián Caicedo-Dávila, et al.
Published: (2024-05-01)
Superior ferroelectricity and nonlinear optical response in a hybrid germanium iodide hexagonal perovskite
by: Kun Ding, et al.
Published: (2023-05-01)
by: Kun Ding, et al.
Published: (2023-05-01)
Origin of the Captodative Effect: The Lone‐Pair Shielded Radical
by: Eva Blokker, et al.
Published: (2023-07-01)
by: Eva Blokker, et al.
Published: (2023-07-01)
On the Quantum Chemical Nature of Lead(II) “Lone Pair”
by: Christophe Gourlaouen, et al.
Published: (2021-12-01)
by: Christophe Gourlaouen, et al.
Published: (2021-12-01)
Feeling lonely and dissatisfied – understanding social network functioning in stroke survivors
by: Jia En Kam, et al.
Published: (2024-10-01)
by: Jia En Kam, et al.
Published: (2024-10-01)
Lone Pair and Unique N‐Bridging of Novel Titanium Nitridophosphate
by: Peter Ufondu, et al.
Published: (2025-04-01)
by: Peter Ufondu, et al.
Published: (2025-04-01)
Vibrational Spectroscopy of Perovskite Ferroelectrics
by: Seiji Kojima
Published: (2024-12-01)
by: Seiji Kojima
Published: (2024-12-01)
Relationship between Pb ion off-centering and lone pair electrons
by: Kosuke Kurushima, et al.
Published: (2025-03-01)
by: Kosuke Kurushima, et al.
Published: (2025-03-01)
Molecular ferroelectric self-assembled interlayer for efficient perovskite solar cells
by: Chang Xu, et al.
Published: (2025-01-01)
by: Chang Xu, et al.
Published: (2025-01-01)
Photo-ferroelectric perovskite interfaces for boosting VOC in efficient perovskite solar cells
by: Giovanni Pica, et al.
Published: (2024-10-01)
by: Giovanni Pica, et al.
Published: (2024-10-01)
Microencapsulation of Lead-Halide Perovskites in an Oil-in-Fluorine Emulsion for Cell Imaging
by: Jia-Xin Wang, et al.
Published: (2023-05-01)
by: Jia-Xin Wang, et al.
Published: (2023-05-01)
PREDICTION OF MULTIAXIAL LOAD FATIGUE LIFE FOR RUBBER BUSHING
by: YIN Fang, et al.
Published: (2020-01-01)
by: YIN Fang, et al.
Published: (2020-01-01)
Sulfur Lone Pairs Control Topology in Heterotrimetallic Complexes: An Experimental and Theoretical Study
by: Paulina Guerrero-Almaraz, et al.
Published: (2023-09-01)
by: Paulina Guerrero-Almaraz, et al.
Published: (2023-09-01)
Improper High‐Tc Perovskite Ferroelectric with Dielectric Bistability Enables Broadband Ultraviolet‐to‐Infrared Photopyroelectric Effects
by: Lina Hua, et al.
Published: (2023-07-01)
by: Lina Hua, et al.
Published: (2023-07-01)
Ferromagnetism and ferroelectricity in a superlattice of antiferromagnetic perovskite oxides without ferroelectric polarization
by: Paresh C. Rout, et al.
Published: (2023-09-01)
by: Paresh C. Rout, et al.
Published: (2023-09-01)
High-efficiency nonlinear frequency conversion enabled by optimizing the ferroelectric domain structure in x-cut LNOI ridge waveguide
by: Su Yawen, et al.
Published: (2024-05-01)
by: Su Yawen, et al.
Published: (2024-05-01)
Anomalous Polarons in Two‐Dimensional Organometallic Perovskite Ferroelectric
by: Junhong Yu, et al.
Published: (2024-11-01)
by: Junhong Yu, et al.
Published: (2024-11-01)
Incipient ferroelectricity in methylammonium lead halide perovskites
by: Alexei A. Bokov, et al.
Published: (2025-04-01)
by: Alexei A. Bokov, et al.
Published: (2025-04-01)
Absence of ferroelectricity in methylammonium lead iodide perovskite
by: Mohammad Sajedi Alvar, et al.
Published: (2017-09-01)
by: Mohammad Sajedi Alvar, et al.
Published: (2017-09-01)
Design of organic crystals with lone pairs to study spin resonance and spin-lattice interactions
by: Shilin Li, et al.
Published: (2025-01-01)
by: Shilin Li, et al.
Published: (2025-01-01)
Lone pair-π interaction induced regioselective sulfonation of ethers under light irradiation
by: Chonglong He, et al.
Published: (2024-05-01)
by: Chonglong He, et al.
Published: (2024-05-01)
Efficient Quasi-2D Perovskite Light-Emitting Diodes Enabled by Regulating Phase Distribution with a Fluorinated Organic Cation
by: Ziqing Ye, et al.
Published: (2022-10-01)
by: Ziqing Ye, et al.
Published: (2022-10-01)
Organic Passivation‐Enhanced Ferroelectricity in Perovskite Oxide Films
by: Hao Meng, et al.
Published: (2024-08-01)
by: Hao Meng, et al.
Published: (2024-08-01)
Fluorinated Organic Cations Derived Chiral 2D Perovskite Enabling Enhanced Spin‐Dependent Oxygen Evolution Reaction
by: Jaehyun Son, et al.
Published: (2024-09-01)
by: Jaehyun Son, et al.
Published: (2024-09-01)
Ferroelectric order in hybrid organic-inorganic perovskite NH4PbI3 with non-polar molecules and small tolerance factor
by: Jia-Bin Li, et al.
Published: (2023-04-01)
by: Jia-Bin Li, et al.
Published: (2023-04-01)
Facile Fabrication of Large‐Area and High‐Quality Organic–Inorganic Hybrid Perovskite Ferroelectric Films Through Electrohydrodynamic Printing
by: Jingjing Luo, et al.
Published: (2025-06-01)
by: Jingjing Luo, et al.
Published: (2025-06-01)
Lonely Landscapes
by: Lydia Kokkola
Published: (2024-04-01)
by: Lydia Kokkola
Published: (2024-04-01)
Lonely times, lonely places: Christopher Isherwood’s chronotopography of loneliness.
by: Anton Drannikov
Published: (2025-01-01)
by: Anton Drannikov
Published: (2025-01-01)
Strain-driven lone pair electron expression for thermal transport in BiCuSeO
by: Da Wan, et al.
Published: (2025-07-01)
by: Da Wan, et al.
Published: (2025-07-01)
Tunable ferroelectricity in oxygen-deficient perovskites with Grenier structure
by: Yongjin Shin, et al.
Published: (2023-12-01)
by: Yongjin Shin, et al.
Published: (2023-12-01)
Quenching effects and mechanisms in bismuth-based perovskite ferroelectrics
by: K.V. Lalitha, et al.
Published: (2022-06-01)
by: K.V. Lalitha, et al.
Published: (2022-06-01)
FATIGUE LIFE PREDICTION METHODOLOGY BASED ON WEIGHT-AVERAGED MAXIMUM SHEAR STRESS PLANE UNDER MULTIAXIAL LOADING
by: TAO ZhiQiang, et al.
Published: (2021-01-01)
by: TAO ZhiQiang, et al.
Published: (2021-01-01)
Improved Photostability in Fluorinated 2D Perovskite Single Crystals
by: Annalisa Coriolano, et al.
Published: (2021-02-01)
by: Annalisa Coriolano, et al.
Published: (2021-02-01)
Review of Response and Damage of Linear and Nonlinear Systems under Multiaxial Vibration
by: Ed Habtour, et al.
Published: (2014-01-01)
by: Ed Habtour, et al.
Published: (2014-01-01)
Modeling of nonlinear multiaxial deformation of concrete on the base of hyperelastic orthotropic model
by: Lavrov Kirill, et al.
Published: (2016-01-01)
by: Lavrov Kirill, et al.
Published: (2016-01-01)
Multiaxial Fatigue Lifetime Estimation Based on New Equivalent Strain Energy Damage Model under Variable Amplitude Loading
by: Zhi-Qiang Tao, et al.
Published: (2024-09-01)
by: Zhi-Qiang Tao, et al.
Published: (2024-09-01)
Organic–Inorganic Hybrid Perovskite Ferroelectric Nanosheets Synthesized by a Room‐Temperature Antisolvent Method
by: Tai‐Ting Sha, et al.
Published: (2024-08-01)
by: Tai‐Ting Sha, et al.
Published: (2024-08-01)
Similar Items
-
Mechanically deformable organic ferroelectric crystal with plasticity optimized by fluorination
by: Pei-Zhi Huang, et al.
Published: (2025-03-01) -
Lone-pair activated ferroelectricity and stable charged domain wall in Bi monolayer
by: Shulin Zhong, et al.
Published: (2024-09-01) -
Methylhydrazine Lone‐Pair Engineering for Polar Lead‐Free Perovskite Enables Self‐Powered X‐Ray Detection
by: Ruiqing Li, et al.
Published: (2025-05-01) -
Disentangling the effects of structure and lone-pair electrons in the lattice dynamics of halide perovskites
by: Sebastián Caicedo-Dávila, et al.
Published: (2024-05-01) -
Superior ferroelectricity and nonlinear optical response in a hybrid germanium iodide hexagonal perovskite
by: Kun Ding, et al.
Published: (2023-05-01)
