Crystal structure of bis(4-acetylpyridine-κN)bis(ethanol-κO)bis(thiocyanato-κN)manganese(II)

In the crystal structure of the title compound, [Mn(NCS)2(C7H7NO)2(C2H5OH)2], the MnII atom is coordinated by two N-bonded thiocyanate anions, two 4-acetylpyridine ligands, and two ethanol molecules within a slightly distorted octahedron. The asymmetric unit consits of one manganese cation, located...

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Bibliographic Details
Published in:Acta Crystallographica Section E: Crystallographic Communications
Main Authors: Julia Werner, Inke Jess, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2015-04-01
Subjects:
crystal structure
manganese(II)
octahedral coordination
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015004533
Description
Summary:In the crystal structure of the title compound, [Mn(NCS)2(C7H7NO)2(C2H5OH)2], the MnII atom is coordinated by two N-bonded thiocyanate anions, two 4-acetylpyridine ligands, and two ethanol molecules within a slightly distorted octahedron. The asymmetric unit consits of one manganese cation, located on a centre of inversion, one thiocyanate anion, one 4-acetylpyridine ligand and one ethanol molecule in general positions. The discrete complexes are connected by intermolecular O—H...O hydrogen bonds between the alcohol OH group and the carbonyl O atom into chains parallel to [011].
ISSN:2056-9890

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