Electrochemical radical cation aza-Wacker cyclizations
Electrochemical or photochemical single-electron oxidation of bench-stable substrates can generate radical cations that offer unique reactivities as intermediates in various bond-formation processes. Such intermediates can potentially take part in both radical and ionic bond formation; however, the...
| 出版年: | Beilstein Journal of Organic Chemistry |
|---|---|
| 主要な著者: | , |
| フォーマット: | 論文 |
| 言語: | 英語 |
| 出版事項: |
Beilstein-Institut
2024-08-01
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| 主題: | |
| オンライン･アクセス: | https://doi.org/10.3762/bjoc.20.165 |
| _version_ | 1850065684006961152 |
|---|---|
| author | Sota Adachi Yohei Okada |
| author_facet | Sota Adachi Yohei Okada |
| author_sort | Sota Adachi |
| collection | DOAJ |
| container_title | Beilstein Journal of Organic Chemistry |
| description | Electrochemical or photochemical single-electron oxidation of bench-stable substrates can generate radical cations that offer unique reactivities as intermediates in various bond-formation processes. Such intermediates can potentially take part in both radical and ionic bond formation; however, the mechanisms involved are complicated and not fully understood. Herein, we report electrochemical radical cation aza-Wacker cyclizations under acidic conditions, which are expected to proceed via radical cations generated by single-electron oxidation of alkenes. |
| format | Article |
| id | doaj-art-59fed5e81a6c415b9bcf71cd08fbcae1 |
| institution | Directory of Open Access Journals |
| issn | 1860-5397 |
| language | English |
| publishDate | 2024-08-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| spelling | doaj-art-59fed5e81a6c415b9bcf71cd08fbcae12025-08-20T00:19:40ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972024-08-012011900190510.3762/bjoc.20.1651860-5397-20-165Electrochemical radical cation aza-Wacker cyclizationsSota Adachi0Yohei Okada1Department of Applied Biological Science, Tokyo University of Agriculture and Technology, 3-5-8 Saiwai-cho, Fuchu, Tokyo 183-8509, Japan Department of Applied Biological Science, Tokyo University of Agriculture and Technology, 3-5-8 Saiwai-cho, Fuchu, Tokyo 183-8509, Japan Electrochemical or photochemical single-electron oxidation of bench-stable substrates can generate radical cations that offer unique reactivities as intermediates in various bond-formation processes. Such intermediates can potentially take part in both radical and ionic bond formation; however, the mechanisms involved are complicated and not fully understood. Herein, we report electrochemical radical cation aza-Wacker cyclizations under acidic conditions, which are expected to proceed via radical cations generated by single-electron oxidation of alkenes.https://doi.org/10.3762/bjoc.20.165alkeneaza-wacker cyclizationelectrochemistryradical cationsulfonamide |
| spellingShingle | Sota Adachi Yohei Okada Electrochemical radical cation aza-Wacker cyclizations alkene aza-wacker cyclization electrochemistry radical cation sulfonamide |
| title | Electrochemical radical cation aza-Wacker cyclizations |
| title_full | Electrochemical radical cation aza-Wacker cyclizations |
| title_fullStr | Electrochemical radical cation aza-Wacker cyclizations |
| title_full_unstemmed | Electrochemical radical cation aza-Wacker cyclizations |
| title_short | Electrochemical radical cation aza-Wacker cyclizations |
| title_sort | electrochemical radical cation aza wacker cyclizations |
| topic | alkene aza-wacker cyclization electrochemistry radical cation sulfonamide |
| url | https://doi.org/10.3762/bjoc.20.165 |
| work_keys_str_mv | AT sotaadachi electrochemicalradicalcationazawackercyclizations AT yoheiokada electrochemicalradicalcationazawackercyclizations |