Pentafluoropropionic Anhydride Derivatization and GC-MS Analysis of Histamine, Agmatine, Putrescine, and Spermidine: Effects of Solvents and Starting Column Temperature

Gas chromatography–mass spectrometry (GC-MS) is useful for the quantitative determination of the polyamines spermidine (SPD) and putrescine (PUT) and of the biogenic amine agmatine (AGM) in biological samples after derivatization. This GC-MS method involves a two-step extraction with <i>n</...

Full description

Bibliographic Details
Published in:	Molecules
Main Authors:	Dimitrios Tsikas, Bibiana Beckmann, Svetlana Baskal, Gorig Brunner
Format:	Article
Language:	English
Published:	MDPI AG 2023-01-01
Subjects:	acylation amidation amines biogenic amines derivatization GC-MS
Online Access:	https://www.mdpi.com/1420-3049/28/3/939

Similar Items

GC-MS Studies on the Conversion and Derivatization of γ-Glutamyl Peptides to Pyroglutamate (5-Oxo-Proline) Methyl Ester Pentafluoropropione Amide Derivatives
by: Alexander Bollenbach, et al.
Published: (2022-09-01)

Simultaneous detection and quantification of different biogenic amines
by: Vishal Kumar, et al.
Published: (2022-09-01)

Evaluation of Biogenic Amines in Organic and Non-Organic Wines by HPLC OPA Derivatization
by: Ali Üren, et al.
Published: (2007-01-01)

Optimization of the Schiff-Base Reaction of Acetylacetone with Biogenic Amines
by: Bediha Akmese, et al.
Published: (2017-06-01)

Accumulation of Agmatine, Spermidine, and Spermine in Sprouts and Microgreens of Alfalfa, Fenugreek, Lentil, and Daikon Radish
by: Irena Kralj Cigić, et al.
Published: (2020-05-01)

Development of a High Performance Liquid Chromatography with Diode Array Detector (HPLC-DAD) Method for Determination of Biogenic Amines in Ripened Cheeses
by: Marzena Pawul-Gruba, et al.
Published: (2022-11-01)

Two-Step Derivatization of Amino Acids for Stable-Isotope Dilution GC–MS Analysis: Long-Term Stability of Methyl Ester-Pentafluoropropionic Derivatives in Toluene Extracts
by: Svetlana Baskal, et al.
Published: (2021-03-01)

Influence of Oenological Processes and Product Qualities on the Compositional Profiles of Biogenic Amines of Sparkling Wines
by: Aina Mir-Cerdà, et al.
Published: (2021-10-01)

The Development of an Ultra-Performance Liquid Chromatography–Tandem Mass Spectrometry Method for Biogenic Amines in Fish Samples
by: Tong Li, et al.
Published: (2022-12-01)

Assessment of Toxic Histamine Contents in Processed Cheeses and the Effect of Salt and pH Levels on the Amount of Histamine
by: T. Heidari, et al.
Published: (2024-12-01)

Stable-Isotope Dilution GC–MS Measurement of Metformin in Human Serum and Urine after Derivatization with Pentafluoropropionic Anhydride and Its Application in Becker Muscular Dystrophy Patients Administered with Metformin, <span style="font-variant: small-caps">l</span>-Citrulline, or Their Combination
by: Svetlana Baskal, et al.
Published: (2022-06-01)

Determination of Biogenic Amines in Different Parts of <i>Lycium barbarum</i> L. by HPLC with Precolumn Dansylation
by: Yun Ai, et al.
Published: (2021-02-01)

Histamine intolerance caused by Diamine Oxidase (DAO) deficiency – case report
by: Aleksandra Iwona Zimna, et al.
Published: (2022-09-01)

Flexible and Printed Electrochemical Immunosensor Coated with Oxygen Plasma Treated SWCNTs for Histamine Detection
by: Bajramshahe Shkodra, et al.
Published: (2020-04-01)

Ratiometric fluorescent test strips based on CB-Ni2+@CDs probes for visual detection of histamine
by: Xiuying Liu, et al.
Published: (2024-06-01)

An Overview of Histamine and Other Biogenic Amines in Fish and Fish Products
by: Pierina Visciano, et al.
Published: (2020-12-01)

Degradation Performance of Biogenic Amines in Fermented Food by Lactobacillus casei FV006
by: Xueli WANG, et al.
Published: (2023-07-01)

Role of Marine Bacterial Contaminants in Histamine Formation in Seafood Products: A Review
by: Adnorita Fandah Oktariani, et al.
Published: (2022-06-01)

Effects of a Novel Starter Culture on Quality Improvement and Putrescine, Cadaverine, and Histamine Inhibition of Fermented Shrimp Paste
by: Xinyu Li, et al.
Published: (2023-07-01)

Characterization of the Biofilms Formed by Histamine-Producing <i>Lentilactobacillus parabuchneri</i> Strains in the Dairy Environment
by: Agustina Sarquis, et al.
Published: (2023-04-01)

Removal of Histamine from Fish Sauce by Staphylococcus debuckii sp. Isolated from Fermented Fish
by: Natthakan Rungraeng, et al.
Published: (2023-01-01)

Integrated Metagenomic and LC–MS/MS Analysis Reveals the Biogenic Amine-Producing Strains of Two Typical Chinese Traditional Fish Products: Fermented Mandarin Fish (<i>Siniperca chuatsi</i>) and Semi-Dried Yellow Croaker (<i>Larimichthys crocea</i>)
by: Xuan Zhang, et al.
Published: (2025-03-01)

Quality Characteristics of Retailed Sucuk (Turkish Dry-Fermented Sausage)
by: Osman Erkmen, et al.
Published: (2004-01-01)

Contents of Polyamines and Biogenic Amines in Canned Pet (Dogs and Cats) Food on the Austrian Market
by: Peter Paulsen, et al.
Published: (2021-10-01)

Investigation of the Biogenic Amine Content in Jiangxi-made Sufu and Isolation and Identification of Amine-producing Bacteria
by: Weiya WANG, et al.
Published: (2022-06-01)

Enhanced γ-aminobutyric acid levels promote degeneration of silk glands following spermidine supplementation in Bombyx mori
by: Brinda Goda Lakshmi Didugu, et al.
Published: (2025-06-01)

Determination of Anthraquinone-Tagged Amines Using High-Performance Liquid Chromatography with Online UV Irradiation and Luminol Chemiluminescence Detection
by: Naoya Kishikawa, et al.
Published: (2023-02-01)

Determination of 5 kinds of biogenic amines in cheeses by high performance liquid chromatography-tandem mass spectrometry
by: ZHANG Hui, et al.
Published: (2023-12-01)

A Galactose-Functionalized Pyrrolopyrrole <i>Aza</i>-BODIPY for Highly Efficient Detection of Eight Aliphatic and Aromatic Biogenic Amines: Monitoring Food Freshness and Bioimaging
by: Yujing Gan, et al.
Published: (2025-08-01)

A Diamine Oxidase from <i>Glutamicibacter halophytocola</i> for the Degradation of Histamine and Tyramine in Foods
by: Lucas Kettner, et al.
Published: (2025-09-01)

GC-MS Studies on Derivatization of Creatinine and Creatine by BSTFA and Their Measurement in Human Urine
by: Olga Begou, et al.
Published: (2021-05-01)

Direct Transamidation Reactions: Mechanism and Recent Advances
by: Paola Acosta-Guzmán, et al.
Published: (2018-09-01)

The Rate of Histamine Degradation by Diamine Oxidase Is Compromised by Other Biogenic Amines
by: Sònia Sánchez-Pérez, et al.
Published: (2022-05-01)

Occurrence and Levels of Biogenic Amines in Beers Produced by Different Methods
by: Katarzyna Nalazek-Rudnicka, et al.
Published: (2021-11-01)

Preliminary Study for Detection of Hydrogen Peroxide Using a Hydroxyethyl Cellulose Membrane
by: Helena Vasconcelos, et al.
Published: (2019-07-01)

Prodotti della tradizione e contenuto di amine biogene alternative alla Low tyramine diet per la sostenibilità dei prodotti di nicchia e la salubrità del consumatore
by: Giovanna Suzzi, et al.
Published: (2011-09-01)

Innovative Sensing Platforms for Toxic Compounds Detection
by: Ana-Maria Gurban, et al.
Published: (2019-10-01)

Biogenic Amines in Gliomas: A Comprehensive Literature Review
by: Ahmad Abuaisheh, et al.
Published: (2023-07-01)

Combined effect of lactic acid, bioactive components and modified atmosphere packaging on the quality of minced meat
by: Anita Rokaityte, et al.
Published: (2016-02-01)

Occurrence of biogenic amines and amines degrading bacteria in fish sauce
by: Muhammad Zukhrufuz Zaman, et al.
Published: (2010-10-01)