Superhydrophobic PVDF membrane formed by crystallization process for direct contact membrane distillation

Summary: With growing demand for freshwater resources, membrane distillation (MD) attracts intensive attention owing to the possibility of reclaiming almost 100% freshwater with superhydrophobic membranes as the pivotal separation units. Current superhydrophobic membrane still suffers relatively com...

詳細記述

書誌詳細
出版年:iScience
主要な著者: Caiyun Hou, Lei Du, Yao Li, Meiwei Guo, Jiti Zhou, Sen Qiao
フォーマット: 論文
言語:英語
出版事項: Elsevier 2023-05-01
主題:
オンライン・アクセス:http://www.sciencedirect.com/science/article/pii/S2589004223005412
_version_ 1850144699111702528
author Caiyun Hou
Lei Du
Yao Li
Meiwei Guo
Jiti Zhou
Sen Qiao
author_facet Caiyun Hou
Lei Du
Yao Li
Meiwei Guo
Jiti Zhou
Sen Qiao
author_sort Caiyun Hou
collection DOAJ
container_title iScience
description Summary: With growing demand for freshwater resources, membrane distillation (MD) attracts intensive attention owing to the possibility of reclaiming almost 100% freshwater with superhydrophobic membranes as the pivotal separation units. Current superhydrophobic membrane still suffers relatively complex preparation process and limited membrane flux. Herein, we developed a promising route to fabricate a high-flux superhydrophobic poly(vinylidene fluoride) (PVDF) membrane by a simple solute and solvent co-crystallization (SSCC) method, which endowed the membrane ultra-high porosity and flux. We also found that the pore size of superhydrophobic membrane can be adjusted by controlling the crystallization process of DMSO, which gave rise to membrane higher flexibility. The membrane exhibited the outperforming desalination performance even in multiple harsh environments including different temperature, salty concentration, and pH, with/without humic acid. The membrane also displayed distinguished anti-fouling performance and long-term stability, which is quite significant for practical application.
format Article
id doaj-art-7cf4fc46efcc473eb5adbcdbf6eb6e6a
institution Directory of Open Access Journals
issn 2589-0042
language English
publishDate 2023-05-01
publisher Elsevier
record_format Article
spelling doaj-art-7cf4fc46efcc473eb5adbcdbf6eb6e6a2025-08-19T23:47:53ZengElsevieriScience2589-00422023-05-0126510646410.1016/j.isci.2023.106464Superhydrophobic PVDF membrane formed by crystallization process for direct contact membrane distillationCaiyun Hou0Lei Du1Yao Li2Meiwei Guo3Jiti Zhou4Sen Qiao5Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, P.R. ChinaKey Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, P.R. ChinaKey Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, P.R. ChinaKey Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, P.R. ChinaKey Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, P.R. ChinaKey Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, P.R. China; Corresponding authorSummary: With growing demand for freshwater resources, membrane distillation (MD) attracts intensive attention owing to the possibility of reclaiming almost 100% freshwater with superhydrophobic membranes as the pivotal separation units. Current superhydrophobic membrane still suffers relatively complex preparation process and limited membrane flux. Herein, we developed a promising route to fabricate a high-flux superhydrophobic poly(vinylidene fluoride) (PVDF) membrane by a simple solute and solvent co-crystallization (SSCC) method, which endowed the membrane ultra-high porosity and flux. We also found that the pore size of superhydrophobic membrane can be adjusted by controlling the crystallization process of DMSO, which gave rise to membrane higher flexibility. The membrane exhibited the outperforming desalination performance even in multiple harsh environments including different temperature, salty concentration, and pH, with/without humic acid. The membrane also displayed distinguished anti-fouling performance and long-term stability, which is quite significant for practical application.http://www.sciencedirect.com/science/article/pii/S2589004223005412MembranesApplied sciences
spellingShingle Caiyun Hou
Lei Du
Yao Li
Meiwei Guo
Jiti Zhou
Sen Qiao
Superhydrophobic PVDF membrane formed by crystallization process for direct contact membrane distillation
Membranes
Applied sciences
title Superhydrophobic PVDF membrane formed by crystallization process for direct contact membrane distillation
title_full Superhydrophobic PVDF membrane formed by crystallization process for direct contact membrane distillation
title_fullStr Superhydrophobic PVDF membrane formed by crystallization process for direct contact membrane distillation
title_full_unstemmed Superhydrophobic PVDF membrane formed by crystallization process for direct contact membrane distillation
title_short Superhydrophobic PVDF membrane formed by crystallization process for direct contact membrane distillation
title_sort superhydrophobic pvdf membrane formed by crystallization process for direct contact membrane distillation
topic Membranes
Applied sciences
url http://www.sciencedirect.com/science/article/pii/S2589004223005412
work_keys_str_mv AT caiyunhou superhydrophobicpvdfmembraneformedbycrystallizationprocessfordirectcontactmembranedistillation
AT leidu superhydrophobicpvdfmembraneformedbycrystallizationprocessfordirectcontactmembranedistillation
AT yaoli superhydrophobicpvdfmembraneformedbycrystallizationprocessfordirectcontactmembranedistillation
AT meiweiguo superhydrophobicpvdfmembraneformedbycrystallizationprocessfordirectcontactmembranedistillation
AT jitizhou superhydrophobicpvdfmembraneformedbycrystallizationprocessfordirectcontactmembranedistillation
AT senqiao superhydrophobicpvdfmembraneformedbycrystallizationprocessfordirectcontactmembranedistillation