Facile and controllable chemical doping of conducting polymers with an ionic liquid dopant

A facile method for chemical doping of conducting polymers is demonstrated with an ionic liquid containing FeCl _4 ^− anions as the oxidizing agents. A drop of the ionic liquid on the film of a typical semicrystalline polymer immediately changed the room temperature conductivity to 500 S cm ^−1 . Th...

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書目詳細資料
發表在:Applied Physics Express
Main Authors: Hisaaki Tanaka, Shun-ichiro Ito, Toru Matsui, Taishi Takenobu
格式: Article
語言:英语
出版: IOP Publishing 2024-01-01
主題:
在線閱讀:https://doi.org/10.35848/1882-0786/ad2f66
實物特徵
總結:A facile method for chemical doping of conducting polymers is demonstrated with an ionic liquid containing FeCl _4 ^− anions as the oxidizing agents. A drop of the ionic liquid on the film of a typical semicrystalline polymer immediately changed the room temperature conductivity to 500 S cm ^−1 . The highly conductive state originated from both the high doping level and the high crystallinity of the doped film, as confirmed by optical absorption and X-ray diffraction measurements, respectively. Furthermore, the doping level was continuously controlled by the gate voltage of the ionic-liquid-gated transistor structure through an electrochemical dedoping process.
ISSN:1882-0786