Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate

This paper presents the results of a study of polymer films based on a blend of low-density (high-pressure) polyethylene (LDPE, HPP) with a copolymer of ethylene and vinyl acetate (EVA, sevilen). The use of thermal activation, infrared and dielectric spectroscopy methods made it possible to describe...

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發表在:St. Petersburg Polytechnical University Journal: Physics and Mathematics
Main Authors: Karulina Elena, Galikhanov Mansur, Castro Arata Rene Alejandro, Reztsov Tikhon, Fomicheva Elena
格式: Article
語言:英语
出版: Peter the Great St.Petersburg Polytechnic University 2024-09-01
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在線閱讀:https://physmath.spbstu.ru/article/2024.74.04/
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author Karulina Elena
Galikhanov Mansur
Castro Arata Rene Alejandro
Reztsov Tikhon
Fomicheva Elena
author_facet Karulina Elena
Galikhanov Mansur
Castro Arata Rene Alejandro
Reztsov Tikhon
Fomicheva Elena
author_sort Karulina Elena
collection DOAJ
container_title St. Petersburg Polytechnical University Journal: Physics and Mathematics
description This paper presents the results of a study of polymer films based on a blend of low-density (high-pressure) polyethylene (LDPE, HPP) with a copolymer of ethylene and vinyl acetate (EVA, sevilen). The use of thermal activation, infrared and dielectric spectroscopy methods made it possible to describe the electric charge relaxation processes in the polymer blends investigated. The data obtained suggested the presence of an α-relaxation process in the samples in the temperature range 250–280 K. An increased value of the activation energy of this process was also found in the LDPE/EVA samples compared to that in the LDPE one. This effect has been interpreted as the appearance of deeper traps of charge carriers in the blends. The dependences obtained by dielectric spectroscopy indicated the presence of hopping conductivity in the subjects of research.
format Article
id doaj-art-ac3ebce9995f43748e4e851176df099f
institution Directory of Open Access Journals
issn 2405-7223
language English
publishDate 2024-09-01
publisher Peter the Great St.Petersburg Polytechnic University
record_format Article
spelling doaj-art-ac3ebce9995f43748e4e851176df099f2025-08-20T01:19:04ZengPeter the Great St.Petersburg Polytechnic UniversitySt. Petersburg Polytechnical University Journal: Physics and Mathematics2405-72232024-09-0117310.18721/JPM.1730420714726Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetateKarulina Elena0https://orcid.org/0000-0001-9604-4769Galikhanov Mansur1Castro Arata Rene Alejandro2https://orcid.org/0000-0002-1902-5801Reztsov Tikhon3https://orcid.org/0000-0003-2025-0579Fomicheva Elena4https://orcid.org/0000-0002-9402-5246Herzen State Pedagogical University of RussiaKazan National Research Technological UniversityHerzen State Pedagogical University of RussiaHerzen State Pedagogical University of RussiaMilitary Space Academy named after A.F. MozhayskyThis paper presents the results of a study of polymer films based on a blend of low-density (high-pressure) polyethylene (LDPE, HPP) with a copolymer of ethylene and vinyl acetate (EVA, sevilen). The use of thermal activation, infrared and dielectric spectroscopy methods made it possible to describe the electric charge relaxation processes in the polymer blends investigated. The data obtained suggested the presence of an α-relaxation process in the samples in the temperature range 250–280 K. An increased value of the activation energy of this process was also found in the LDPE/EVA samples compared to that in the LDPE one. This effect has been interpreted as the appearance of deeper traps of charge carriers in the blends. The dependences obtained by dielectric spectroscopy indicated the presence of hopping conductivity in the subjects of research.https://physmath.spbstu.ru/article/2024.74.04/polyethylenecopolymer of ethylene with vinyl acetatethermostimulated depolarizationthermo-activation spectroscopy
spellingShingle Karulina Elena
Galikhanov Mansur
Castro Arata Rene Alejandro
Reztsov Tikhon
Fomicheva Elena
Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate
polyethylene
copolymer of ethylene with vinyl acetate
thermostimulated depolarization
thermo-activation spectroscopy
title Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate
title_full Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate
title_fullStr Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate
title_full_unstemmed Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate
title_short Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate
title_sort relaxation of electric charge in polymer blends based on low density polyethylene and copolymer of ethylene with vinyl acetate
topic polyethylene
copolymer of ethylene with vinyl acetate
thermostimulated depolarization
thermo-activation spectroscopy
url https://physmath.spbstu.ru/article/2024.74.04/
work_keys_str_mv AT karulinaelena relaxationofelectricchargeinpolymerblendsbasedonlowdensitypolyethyleneandcopolymerofethylenewithvinylacetate
AT galikhanovmansur relaxationofelectricchargeinpolymerblendsbasedonlowdensitypolyethyleneandcopolymerofethylenewithvinylacetate
AT castroaratarenealejandro relaxationofelectricchargeinpolymerblendsbasedonlowdensitypolyethyleneandcopolymerofethylenewithvinylacetate
AT reztsovtikhon relaxationofelectricchargeinpolymerblendsbasedonlowdensitypolyethyleneandcopolymerofethylenewithvinylacetate
AT fomichevaelena relaxationofelectricchargeinpolymerblendsbasedonlowdensitypolyethyleneandcopolymerofethylenewithvinylacetate