Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate
This paper presents the results of a study of polymer films based on a blend of low-density (high-pressure) polyethylene (LDPE, HPP) with a copolymer of ethylene and vinyl acetate (EVA, sevilen). The use of thermal activation, infrared and dielectric spectroscopy methods made it possible to describe...
| 發表在: | St. Petersburg Polytechnical University Journal: Physics and Mathematics |
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| Main Authors: | , , , , |
| 格式: | Article |
| 語言: | 英语 |
| 出版: |
Peter the Great St.Petersburg Polytechnic University
2024-09-01
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| 主題: | |
| 在線閱讀: | https://physmath.spbstu.ru/article/2024.74.04/ |
| _version_ | 1849861494478471168 |
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| author | Karulina Elena Galikhanov Mansur Castro Arata Rene Alejandro Reztsov Tikhon Fomicheva Elena |
| author_facet | Karulina Elena Galikhanov Mansur Castro Arata Rene Alejandro Reztsov Tikhon Fomicheva Elena |
| author_sort | Karulina Elena |
| collection | DOAJ |
| container_title | St. Petersburg Polytechnical University Journal: Physics and Mathematics |
| description | This paper presents the results of a study of polymer films based on a blend of low-density (high-pressure) polyethylene (LDPE, HPP) with a copolymer of ethylene and vinyl acetate (EVA, sevilen). The use of thermal activation, infrared and dielectric spectroscopy methods made it possible to describe the electric charge relaxation processes in the polymer blends investigated. The data obtained suggested the presence of an α-relaxation process in the samples in the temperature range 250–280 K. An increased value of the activation energy of this process was also found in the LDPE/EVA samples compared to that in the LDPE one. This effect has been interpreted as the appearance of deeper traps of charge carriers in the blends. The dependences obtained by dielectric spectroscopy indicated the presence of hopping conductivity in the subjects of research. |
| format | Article |
| id | doaj-art-ac3ebce9995f43748e4e851176df099f |
| institution | Directory of Open Access Journals |
| issn | 2405-7223 |
| language | English |
| publishDate | 2024-09-01 |
| publisher | Peter the Great St.Petersburg Polytechnic University |
| record_format | Article |
| spelling | doaj-art-ac3ebce9995f43748e4e851176df099f2025-08-20T01:19:04ZengPeter the Great St.Petersburg Polytechnic UniversitySt. Petersburg Polytechnical University Journal: Physics and Mathematics2405-72232024-09-0117310.18721/JPM.1730420714726Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetateKarulina Elena0https://orcid.org/0000-0001-9604-4769Galikhanov Mansur1Castro Arata Rene Alejandro2https://orcid.org/0000-0002-1902-5801Reztsov Tikhon3https://orcid.org/0000-0003-2025-0579Fomicheva Elena4https://orcid.org/0000-0002-9402-5246Herzen State Pedagogical University of RussiaKazan National Research Technological UniversityHerzen State Pedagogical University of RussiaHerzen State Pedagogical University of RussiaMilitary Space Academy named after A.F. MozhayskyThis paper presents the results of a study of polymer films based on a blend of low-density (high-pressure) polyethylene (LDPE, HPP) with a copolymer of ethylene and vinyl acetate (EVA, sevilen). The use of thermal activation, infrared and dielectric spectroscopy methods made it possible to describe the electric charge relaxation processes in the polymer blends investigated. The data obtained suggested the presence of an α-relaxation process in the samples in the temperature range 250–280 K. An increased value of the activation energy of this process was also found in the LDPE/EVA samples compared to that in the LDPE one. This effect has been interpreted as the appearance of deeper traps of charge carriers in the blends. The dependences obtained by dielectric spectroscopy indicated the presence of hopping conductivity in the subjects of research.https://physmath.spbstu.ru/article/2024.74.04/polyethylenecopolymer of ethylene with vinyl acetatethermostimulated depolarizationthermo-activation spectroscopy |
| spellingShingle | Karulina Elena Galikhanov Mansur Castro Arata Rene Alejandro Reztsov Tikhon Fomicheva Elena Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate polyethylene copolymer of ethylene with vinyl acetate thermostimulated depolarization thermo-activation spectroscopy |
| title | Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate |
| title_full | Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate |
| title_fullStr | Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate |
| title_full_unstemmed | Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate |
| title_short | Relaxation of electric charge in polymer blends based on low-density polyethylene and copolymer of ethylene with vinyl acetate |
| title_sort | relaxation of electric charge in polymer blends based on low density polyethylene and copolymer of ethylene with vinyl acetate |
| topic | polyethylene copolymer of ethylene with vinyl acetate thermostimulated depolarization thermo-activation spectroscopy |
| url | https://physmath.spbstu.ru/article/2024.74.04/ |
| work_keys_str_mv | AT karulinaelena relaxationofelectricchargeinpolymerblendsbasedonlowdensitypolyethyleneandcopolymerofethylenewithvinylacetate AT galikhanovmansur relaxationofelectricchargeinpolymerblendsbasedonlowdensitypolyethyleneandcopolymerofethylenewithvinylacetate AT castroaratarenealejandro relaxationofelectricchargeinpolymerblendsbasedonlowdensitypolyethyleneandcopolymerofethylenewithvinylacetate AT reztsovtikhon relaxationofelectricchargeinpolymerblendsbasedonlowdensitypolyethyleneandcopolymerofethylenewithvinylacetate AT fomichevaelena relaxationofelectricchargeinpolymerblendsbasedonlowdensitypolyethyleneandcopolymerofethylenewithvinylacetate |
