Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms
With the using of a thermographic method reaction of oxidation of dibutylsulfide in a noctane 95,6 % concentrated solution of hydrogen peroxide in the mixture reactor with the propeller mixer is studied.It is established that dibutylsulfide oxidation by hydrogen peroxide in an ekvimoly-a...
| Published in: | Известия высших учебных заведений: Проблемы энергетики |
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| Main Authors: | , |
| Format: | Article |
| Language: | English |
| Published: |
Kazan State Power Engineering University
2019-06-01
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| Subjects: | |
| Online Access: | https://www.energyret.ru/jour/article/view/916 |
| Summary: | With the using of a thermographic method reaction of oxidation of dibutylsulfide in a noctane 95,6 % concentrated solution of hydrogen peroxide in the mixture reactor with the propeller mixer is studied.It is established that dibutylsulfide oxidation by hydrogen peroxide in an ekvimoly-arny ratio 1:1 at a temperature of 80 °C proceeds before formation of a dibutilsulfoksid, and at a ratio 1:2 and at a temperature of 100 °C – to a dibutilsulfon.The increase in amount of hydrogen peroxide and temperature is followed by for-mation of sour products – the sulfoniyevykh and sulfonew acids.By method of a gas-liquid chromatography it is proved that during oxidation of dibutylsulfide by hydrogen peroxide his destruction doesn't happen. |
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| ISSN: | 1998-9903 |