Dimorpholinium tetrachloridocobaltate(II)
In the title molecular salt, (C4H10NO)2[CoCl4], the morpholinium cations adopt chair conformations and the tetrachloridocobaltate(II) anion is significantly distorted from regular tetrahedral geometry [Cl—Co—Cl = 102.183 (19)–117.59&#81...
| Published in: | Acta Crystallographica Section E |
|---|---|
| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-09-01
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812035830 |
| _version_ | 1852712324102619136 |
|---|---|
| author | Xing-Xing Cao He-Long Cheng Qing-Liu Feng Li-Zhuang Chen |
| author_facet | Xing-Xing Cao He-Long Cheng Qing-Liu Feng Li-Zhuang Chen |
| author_sort | Xing-Xing Cao |
| collection | DOAJ |
| container_title | Acta Crystallographica Section E |
| description | In the title molecular salt, (C4H10NO)2[CoCl4], the morpholinium cations adopt chair conformations and the tetrachloridocobaltate(II) anion is significantly distorted from regular tetrahedral geometry [Cl—Co—Cl = 102.183 (19)–117.59 (2)°]. The Co—Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N—H...O and N—H...Cl and bifurcated N—H...(O,Cl) hydrogen bonds to generate (100) sheets. |
| format | Article |
| id | doaj-art-bfad1c5b733a4e2d8eecd4c2e680a50f |
| institution | Directory of Open Access Journals |
| issn | 1600-5368 |
| language | English |
| publishDate | 2012-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| spelling | doaj-art-bfad1c5b733a4e2d8eecd4c2e680a50f2025-08-19T21:15:53ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689m1198m119810.1107/S1600536812035830Dimorpholinium tetrachloridocobaltate(II)Xing-Xing CaoHe-Long ChengQing-Liu FengLi-Zhuang ChenIn the title molecular salt, (C4H10NO)2[CoCl4], the morpholinium cations adopt chair conformations and the tetrachloridocobaltate(II) anion is significantly distorted from regular tetrahedral geometry [Cl—Co—Cl = 102.183 (19)–117.59 (2)°]. The Co—Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N—H...O and N—H...Cl and bifurcated N—H...(O,Cl) hydrogen bonds to generate (100) sheets.http://scripts.iucr.org/cgi-bin/paper?S1600536812035830 |
| spellingShingle | Xing-Xing Cao He-Long Cheng Qing-Liu Feng Li-Zhuang Chen Dimorpholinium tetrachloridocobaltate(II) |
| title | Dimorpholinium tetrachloridocobaltate(II) |
| title_full | Dimorpholinium tetrachloridocobaltate(II) |
| title_fullStr | Dimorpholinium tetrachloridocobaltate(II) |
| title_full_unstemmed | Dimorpholinium tetrachloridocobaltate(II) |
| title_short | Dimorpholinium tetrachloridocobaltate(II) |
| title_sort | dimorpholinium tetrachloridocobaltate ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812035830 |
| work_keys_str_mv | AT xingxingcao dimorpholiniumtetrachloridocobaltateii AT helongcheng dimorpholiniumtetrachloridocobaltateii AT qingliufeng dimorpholiniumtetrachloridocobaltateii AT lizhuangchen dimorpholiniumtetrachloridocobaltateii |