Laboratory Investigation of CO2-driven Enhancement of Radiolytic H2O2 on Europa and Other Icy Moons

Observations of Europa’s leading hemisphere reveal elevated H _2 O _2 in the warmer, low-latitude chaos terrains compared to the colder, polar regions. This distribution disagrees with prior laboratory radiolysis studies of pure water ice, which show higher H _2 O _2 yields at colder temperatures. T...

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Bibliographic Details
Published in:The Planetary Science Journal
Main Authors: Bereket D. Mamo, Ujjwal Raut, Ben D. Teolis, Trevor P. Erwin, Richard J. Cartwright, Silvia Protopapa, Kurt D. Retherford, Tom A. Nordheim
Format: Article
Language:English
Published: IOP Publishing 2025-01-01
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Online Access:https://doi.org/10.3847/PSJ/ade3d8
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Summary:Observations of Europa’s leading hemisphere reveal elevated H _2 O _2 in the warmer, low-latitude chaos terrains compared to the colder, polar regions. This distribution disagrees with prior laboratory radiolysis studies of pure water ice, which show higher H _2 O _2 yields at colder temperatures. The regions with higher peroxide abundance, Tara and Powys Regiones, also present increased amounts of CO _2 , possibly sourced from Europa’s interior. To investigate whether CO _2 influences radiolysis of water ice to boost H _2 O _2 production, we irradiated water ice doped with varying amounts of CO _2 with 10 keV electrons at 70 and 100 K. Our results indicate that CO _2 , even in trace amounts (<3%), significantly enhances H _2 O _2 yields at temperatures relevant to Europa. We discuss the mechanisms by which CO _2 boosts peroxide synthesis and quantify H _2 O _2 creation and destruction cross sections and G -values across different CO _2 concentrations. These findings provide a plausible explanation for the perplexing H _2 O _2 distribution on Europa and has implications for understanding peroxide on other icy bodies such as Ganymede and Charon, where it has been detected alongside CO _2 .
ISSN:2632-3338