Synthesis, identification and application of a new ionic liquid based on 1-vinylimidazole, immobilized on graphene oxide nanosheets

In this research, a novel catalyst GO@[PBVIm]HSO4, which is an acidic polymer ionic liquid supported on a graphene oxide substrate, was synthesized. First, (3-aminopropyl) triethoxysilane was attached as a linker to the prepared graphene oxide. In the next step, 1-butyl vinyl imidazolium bromide was...

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Published in:Case Studies in Chemical and Environmental Engineering
Main Authors: Masoumeh Mirhasani, Reza Sandaroos, Behrooz Maleki, Sahar Peiman
Format: Article
Language:English
Published: Elsevier 2025-06-01
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666016424004572
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author Masoumeh Mirhasani
Reza Sandaroos
Behrooz Maleki
Sahar Peiman
author_facet Masoumeh Mirhasani
Reza Sandaroos
Behrooz Maleki
Sahar Peiman
author_sort Masoumeh Mirhasani
collection DOAJ
container_title Case Studies in Chemical and Environmental Engineering
description In this research, a novel catalyst GO@[PBVIm]HSO4, which is an acidic polymer ionic liquid supported on a graphene oxide substrate, was synthesized. First, (3-aminopropyl) triethoxysilane was attached as a linker to the prepared graphene oxide. In the next step, 1-butyl vinyl imidazolium bromide was used to synthesize the expected polymer catalyst on a solid support. The efficiency of this catalyst was used in various organic chemical reactions such as the synthesis of chromene, xanthene, and dihydropyrimidinone derivatives. Short reaction time, suitable temperature, excellent yield of products, and very good activity of recycled catalyst are among the advantages of this heterogeneous catalyst synthesis.
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spelling doaj-art-ccfa72c8e7d64cd0963548c6184dcd562025-08-20T02:57:24ZengElsevierCase Studies in Chemical and Environmental Engineering2666-01642025-06-011110106310.1016/j.cscee.2024.101063Synthesis, identification and application of a new ionic liquid based on 1-vinylimidazole, immobilized on graphene oxide nanosheetsMasoumeh Mirhasani0Reza Sandaroos1Behrooz Maleki2Sahar Peiman3Department of Chemistry, Faculty of Sciences, University of Birjand, Birjand, IranDepartment of Chemistry, Faculty of Sciences, University of Birjand, Birjand, Iran; Corresponding author.Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran; Corresponding author.Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, IranIn this research, a novel catalyst GO@[PBVIm]HSO4, which is an acidic polymer ionic liquid supported on a graphene oxide substrate, was synthesized. First, (3-aminopropyl) triethoxysilane was attached as a linker to the prepared graphene oxide. In the next step, 1-butyl vinyl imidazolium bromide was used to synthesize the expected polymer catalyst on a solid support. The efficiency of this catalyst was used in various organic chemical reactions such as the synthesis of chromene, xanthene, and dihydropyrimidinone derivatives. Short reaction time, suitable temperature, excellent yield of products, and very good activity of recycled catalyst are among the advantages of this heterogeneous catalyst synthesis.http://www.sciencedirect.com/science/article/pii/S2666016424004572Graphene oxideIonic liquidsNanoparticlesPolymer ionic liquid
spellingShingle Masoumeh Mirhasani
Reza Sandaroos
Behrooz Maleki
Sahar Peiman
Synthesis, identification and application of a new ionic liquid based on 1-vinylimidazole, immobilized on graphene oxide nanosheets
Graphene oxide
Ionic liquids
Nanoparticles
Polymer ionic liquid
title Synthesis, identification and application of a new ionic liquid based on 1-vinylimidazole, immobilized on graphene oxide nanosheets
title_full Synthesis, identification and application of a new ionic liquid based on 1-vinylimidazole, immobilized on graphene oxide nanosheets
title_fullStr Synthesis, identification and application of a new ionic liquid based on 1-vinylimidazole, immobilized on graphene oxide nanosheets
title_full_unstemmed Synthesis, identification and application of a new ionic liquid based on 1-vinylimidazole, immobilized on graphene oxide nanosheets
title_short Synthesis, identification and application of a new ionic liquid based on 1-vinylimidazole, immobilized on graphene oxide nanosheets
title_sort synthesis identification and application of a new ionic liquid based on 1 vinylimidazole immobilized on graphene oxide nanosheets
topic Graphene oxide
Ionic liquids
Nanoparticles
Polymer ionic liquid
url http://www.sciencedirect.com/science/article/pii/S2666016424004572
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AT behroozmaleki synthesisidentificationandapplicationofanewionicliquidbasedon1vinylimidazoleimmobilizedongrapheneoxidenanosheets
AT saharpeiman synthesisidentificationandapplicationofanewionicliquidbasedon1vinylimidazoleimmobilizedongrapheneoxidenanosheets