α″ martensite engineering: A strategy to achieve high yield strength and low yield ratio synergy for dual-phase titanium alloy

To breakthrough the long-term contradictory issue of high yield strength and low yield ratio for titanium alloys, and achieving the superior balance between these two key mechanical parameters. We have proposed an efficient “Quenching → Cold deformation → Recrystallization annealing” (QCR) strategy,...

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Published in:Materials & Design
Main Authors: Diao-Feng Li, Chun-Guang Bai, Zhi-Qiang Zhang, Ran Wang, Nan Li, Rui Yang
Format: Article
Language:English
Published: Elsevier 2024-03-01
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S0264127524001369
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author Diao-Feng Li
Chun-Guang Bai
Zhi-Qiang Zhang
Ran Wang
Nan Li
Rui Yang
author_facet Diao-Feng Li
Chun-Guang Bai
Zhi-Qiang Zhang
Ran Wang
Nan Li
Rui Yang
author_sort Diao-Feng Li
collection DOAJ
container_title Materials & Design
description To breakthrough the long-term contradictory issue of high yield strength and low yield ratio for titanium alloys, and achieving the superior balance between these two key mechanical parameters. We have proposed an efficient “Quenching → Cold deformation → Recrystallization annealing” (QCR) strategy, which realizes the high yield strength (900 MPa) and low yield ratio (0.74) synergy for a model Ti6Al4V5.5Cu (wt.%) alloy which characterized with the unique multi-scale heterogeneous structure. The developed QCR processing route is based on the subtle utilization of orthorhombic α″ martensite, which plays the various roles in each processing step. By elaborately manipulating the recrystallization degree, chemical stability, effective domain of β phase and αt nano-precipitates in β phase, the stress-induced α″ martensite transformation (SIM α″) can be controlled effectively and even postponed until after yielding induced by dislocation mechanisms, thus leading to substantially improvement of yield strength. After yielding, abundant proliferation of SIM α″which assisted by multi-scale α phases and their interactions are the fundamental reasons for achieving higher work-hardening ability, tensile strength (1215 MPa) and uniform elongation (11%). Thus, the core strategy to realize the excellent combination of high yield strength and low yield ratio is manipulating the activation sequence of the plastic deformation carriers.
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spelling doaj-art-cdac4e6bc3d5400a9807202252526fbb2025-08-19T23:41:49ZengElsevierMaterials & Design0264-12752024-03-0123911276410.1016/j.matdes.2024.112764α″ martensite engineering: A strategy to achieve high yield strength and low yield ratio synergy for dual-phase titanium alloyDiao-Feng Li0Chun-Guang Bai1Zhi-Qiang Zhang2Ran Wang3Nan Li4Rui Yang5Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China; Shi-changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, ChinaInstitute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China; Shi-changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China; School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China; Corresponding authors at: Shi-changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China.Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China; Shi-changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, ChinaInstitute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China; Shi-changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, ChinaInstitute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China; Shi-changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China; Corresponding authors at: Shi-changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China.Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China; Shi-changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China; School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, ChinaTo breakthrough the long-term contradictory issue of high yield strength and low yield ratio for titanium alloys, and achieving the superior balance between these two key mechanical parameters. We have proposed an efficient “Quenching → Cold deformation → Recrystallization annealing” (QCR) strategy, which realizes the high yield strength (900 MPa) and low yield ratio (0.74) synergy for a model Ti6Al4V5.5Cu (wt.%) alloy which characterized with the unique multi-scale heterogeneous structure. The developed QCR processing route is based on the subtle utilization of orthorhombic α″ martensite, which plays the various roles in each processing step. By elaborately manipulating the recrystallization degree, chemical stability, effective domain of β phase and αt nano-precipitates in β phase, the stress-induced α″ martensite transformation (SIM α″) can be controlled effectively and even postponed until after yielding induced by dislocation mechanisms, thus leading to substantially improvement of yield strength. After yielding, abundant proliferation of SIM α″which assisted by multi-scale α phases and their interactions are the fundamental reasons for achieving higher work-hardening ability, tensile strength (1215 MPa) and uniform elongation (11%). Thus, the core strategy to realize the excellent combination of high yield strength and low yield ratio is manipulating the activation sequence of the plastic deformation carriers.http://www.sciencedirect.com/science/article/pii/S0264127524001369Titanium alloyα″ martensiteYield ratioStress-induced martensite transformationHeterogeneous structure design
spellingShingle Diao-Feng Li
Chun-Guang Bai
Zhi-Qiang Zhang
Ran Wang
Nan Li
Rui Yang
α″ martensite engineering: A strategy to achieve high yield strength and low yield ratio synergy for dual-phase titanium alloy
Titanium alloy
α″ martensite
Yield ratio
Stress-induced martensite transformation
Heterogeneous structure design
title α″ martensite engineering: A strategy to achieve high yield strength and low yield ratio synergy for dual-phase titanium alloy
title_full α″ martensite engineering: A strategy to achieve high yield strength and low yield ratio synergy for dual-phase titanium alloy
title_fullStr α″ martensite engineering: A strategy to achieve high yield strength and low yield ratio synergy for dual-phase titanium alloy
title_full_unstemmed α″ martensite engineering: A strategy to achieve high yield strength and low yield ratio synergy for dual-phase titanium alloy
title_short α″ martensite engineering: A strategy to achieve high yield strength and low yield ratio synergy for dual-phase titanium alloy
title_sort α martensite engineering a strategy to achieve high yield strength and low yield ratio synergy for dual phase titanium alloy
topic Titanium alloy
α″ martensite
Yield ratio
Stress-induced martensite transformation
Heterogeneous structure design
url http://www.sciencedirect.com/science/article/pii/S0264127524001369
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