Supramolecular assembly of covalently modified Anderson-type polyoxometalates and crown ethers towards pseudo-rotaxane structures

The supramolecular assembly of a series of covalently modified Anderson-type polyoxometalates (POMs) and 18-crown-6 ethers was investigated for the first time. Seven new POM–crown ether complexes were prepared by varying the countercations and the modification mode of the Anderson clusters, and they...

Full description

Bibliographic Details
Published in:	Polyoxometalates
Main Authors:	Yi-An Yin, Wu-Ji Chen, Chun-Yan Liu, Meng-Meng Zhang, Chang-Gen Lin, Haralampos N. Miras, Yu-Fei Song
Format:	Article
Language:	English
Published:	Tsinghua University Press 2025-03-01
Subjects:	polyoxometalate supramolecular assembly organic-inorganic hybrid crown ether rotaxane
Online Access:	https://www.sciopen.com/article/10.26599/POM.2024.9140081

Similar Items

Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate
by: Fengping Xiao, et al.
Published: (2024-06-01)

Lignin–Cobalt Nano-Enabled Poly(pseudo)rotaxane Supramolecular Hydrogel for Treating Chronic Wounds
by: Giulia Crivello, et al.
Published: (2023-06-01)

Synthesis and Structural Analysis of a Nitrobenzofurazan Derivative of Dibenzo-18-Crown-6 Ether
by: Alexandru Bujor, et al.
Published: (2022-12-01)

Tying a knot between crown ethers and porphyrins
by: Maksym Matviyishyn, et al.
Published: (2023-10-01)

3,3'-Linked BINOL macrocycles: optimized synthesis of crown ethers featuring one or two BINOL units
by: Somayyeh Kheirjou, et al.
Published: (2025-08-01)

Co-Assembled Supramolecular Organohydrogels of Amphiphilic Zwitterion and Polyoxometalate with Controlled Microstructures
by: Peilin Wei, et al.
Published: (2024-05-01)

How Secondary and Tertiary Amide Moieties are Molecular Stations for Dibenzo-24-crown-8 in [2]Rotaxane Molecular Shuttles?
by: Benjamin Riss-Yaw, et al.
Published: (2017-11-01)

Preparation and properties of MDA-BAPP-BTDA copolyimide/18-crown ether-6 supramolecular films with inclusion structure and ultralow dielectric constants
by: Chunguang Xiao, et al.
Published: (2021-01-01)

Preparation and Spectroscopic Characterization of Iron(III) Complexes of a Functionalized Crown Ether
by: Raed A. Aubed
Published: (2019-05-01)

Preparation and Spectroscopic Characterization of Iron(III) Complexes of a Functionalized Crown Ether
by: Raed A. Aubed
Published: (2019-05-01)

Preparation and Spectroscopic Characterization of Iron(III) Complexes of a Functionalized Crown Ether
by: Raed A. Aubed
Published: (2019-05-01)

Cyclodextrin Rotaxanes of Pt Complexes and Their Conversion to Pt Nanoparticles
by: Yuji Suzaki, et al.
Published: (2020-11-01)

Self-Assembly in Polyoxometalate and Metal Coordination-Based Systems: Synthetic Approaches and Developments
by: Stamatis Passadis, et al.
Published: (2018-07-01)

Covalently Immobilizable Tris(Pyridino)-Crown Ether for Separation of Amines Based on Their Degree of Substitution
by: Panna Vezse, et al.
Published: (2022-04-01)

A Versatile Axle for the Construction of Disassemblage Rotaxanes
by: Lucas A. Powers, et al.
Published: (2016-08-01)

Circularly Polarized Luminescence in Rotaxanes and Catenanes
by: Dr. Arthur H. G. David, et al.
Published: (2025-05-01)

Rotaxane‐Functionalized Dyes for Charge‐Rectification in p‐Type Photoelectrochemical Devices
by: Tessel Bouwens, et al.
Published: (2024-03-01)

Heteroditopic Rotaxanes and Catenanes for Ion Pair Recognition
by: Steven J. Nicholson, et al.
Published: (2023-01-01)

Template Directed Syntheses of Electrochemically Active [2]Rotaxanes: Anion Binding and Redox Studies
by: Mandira Nandi, et al.
Published: (2020-02-01)

Extraction and Complexing Abilities of a Series of p-Tert-butylcalix[4]arenes Substituted by N-carbonylmonoaza-12-crown-4
by: Elena Alekseeva, et al.
Published: (2023-11-01)

Synthetic Modifications of a Pb<sup>2+</sup>-Sensor Acridono-Crown Ether for Covalent Attachment and Their Effects on Selectivity
by: Panna Vezse, et al.
Published: (2024-03-01)

Conductometric study of ligand structure influence on the Pb(II) complexation with crown ethers
by: Edita Bjelić, et al.
Published: (2020-11-01)

Ab Initio Calculations on the Ground and Excited Electronic States of Thorium–Ammonia, Thorium–Aza-Crown, and Thorium–Crown Ether Complexes
by: Zhongyuan Lu, et al.
Published: (2023-06-01)

Perspective of polyoxometalate complexes on flexible assembly and integrated potentials
by: Bao Li, et al.
Published: (2023-03-01)

Pyrolysis conversion of crown-ether-based covalent networks to kagome metal-organic frameworks on Au(111) and Ag(111)
by: Yifan Liang, et al.
Published: (2025-04-01)

Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds
by: Rosa M. Gomila, et al.
Published: (2004-04-01)

Controlling the dispersion of supported polyoxometalate heterogeneous catalysts: impact of hybridization and the role of hydrophilicity–hydrophobicity balance and supramolecularity
by: Gijo Raj, et al.
Published: (2014-10-01)

Thorium Recovery with Crown Ether–Polymer Composite Membranes
by: Aurelia Cristina Nechifor, et al.
Published: (2024-10-01)

A Supramolecular Catalyst Self-Assembled From Polyoxometalates and Cationic Pillar[5]arenes for the Room Temperature Oxidation of Aldehydes
by: Mengyan Zeng, et al.
Published: (2018-10-01)

Microwave Irradiation-Assisted Synthesis of a Novel Crown Ether Crosslinked Chitosan as a Chelating Agent for Heavy Metal Ions (M+n)
by: Ibrahim A. Alsarra, et al.
Published: (2010-09-01)

Probing cations recognized by a crown ether with the 3D-RISM theory. II. 18-crown-6 ether
by: Y.Maruyama, et al.
Published: (2007-09-01)

<i>per</i>-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane
by: Nicholas Pearce, et al.
Published: (2020-04-01)

Heterocyclic Crown Ethers with Potential Biological and Pharmacological Properties: From Synthesis to Applications
by: Faiz Ullah, et al.
Published: (2022-01-01)

Artificial Molecular Machines Powered by Light
by: Matteo Amelia, et al.
Published: (2008-04-01)

Recognition Selectivities of Lasso-Type Pseudo[1]rotaxane Based on a Mono-Ester-Functionalized Pillar[5]arene
by: Wen-Xue Zhang, et al.
Published: (2019-07-01)

The Synthesis, Structure, and Dielectric Properties of a One-Dimensional Hydrogen-Bonded DL-α-Phenylglycine Supramolecular Crown-Ether-Based Inclusion Compound
by: Yang Liu, et al.
Published: (2023-11-01)

Preparation of Crown Ether-Containing Polyamide Membranes via Interfacial Polymerization and Their Desalination Performance
by: Liqing Xing, et al.
Published: (2025-03-01)

Research progress on lithium isotopes separation by chemical exchange with crown ethers decorated materials
by: Yi Fang, et al.
Published: (2025-03-01)

A Bis(Acridino)-Crown Ether for Recognizing Oligoamines in Spermine Biosynthesis
by: Péter Kisfaludi, et al.
Published: (2024-09-01)

Molecular interactions at the interface: polyoxometalates of the Anderson-Evans type and lipid membranes
by: Alina A. Pashkovskaya, et al.
Published: (2024-10-01)