catena-Poly[(aquadimethanolzinc)-μ-furan-2,5-dicarboxylato-κ3O2:O2,O2′]

In the crystal structure of the title compound, [Zn(C6H2O5)(CH3OH)2(H2O)]n, an infinite chain is formed along the b axis by linking of the Zn(OH2)(CH3OH)2 unit with one carboxylate group of the furan-2,5-dicarboxylate ligand. The ZnII ion is in a distorted octahedral environment with one weak coordi...

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Bibliographic Details
Published in:Acta Crystallographica Section E
Main Authors: Wen-Yuan Gao, Yue Gao, Xiao-Lin Qin, Ya-Feng Li, Yue Xu
Format: Article
Language:English
Published: International Union of Crystallography 2012-05-01
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812014936
Description
Summary:In the crystal structure of the title compound, [Zn(C6H2O5)(CH3OH)2(H2O)]n, an infinite chain is formed along the b axis by linking of the Zn(OH2)(CH3OH)2 unit with one carboxylate group of the furan-2,5-dicarboxylate ligand. The ZnII ion is in a distorted octahedral environment with one weak coordination [Zn—Ocarboxylate = 2.565 (3) Å] and two methanol molecules located in axial positions. In the chain, Owater—H...O hydrogen bonds are present, while adjacent chains are linked by Omethanol—H...O hydrogen bonds into a layer parallel to (10-2).
ISSN:1600-5368

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