Selective Growth of Vertical-aligned ZnO Nanorod Arrays on Si Substrate by Catalyst-free Thermal Evaporation

<p>Abstract</p><p>By thermal evaporation of pure ZnO powders, high-density vertical-aligned ZnO nanorod arrays with diameter ranged in 80&#8211;250 nm were successfully synthesized on Si substrates covered with ZnO seed layers. It was revealed that the morphology, orientation,...

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Published in:Nanoscale Research Letters
Main Authors: Jiang Y, Wang H, Zhang ZP, Wang XN, Mo Q, Wang Y, Zhu JH, Wang HB, Yang FJ
Format: Article
Language:English
Published: SpringerOpen 2008-01-01
Subjects:
Online Access:http://dx.doi.org/10.1007/s11671-008-9156-y
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author Jiang Y
Wang H
Zhang ZP
Wang XN
Mo Q
Wang Y
Zhu JH
Wang HB
Yang FJ
author_facet Jiang Y
Wang H
Zhang ZP
Wang XN
Mo Q
Wang Y
Zhu JH
Wang HB
Yang FJ
author_sort Jiang Y
collection DOAJ
container_title Nanoscale Research Letters
description <p>Abstract</p><p>By thermal evaporation of pure ZnO powders, high-density vertical-aligned ZnO nanorod arrays with diameter ranged in 80&#8211;250 nm were successfully synthesized on Si substrates covered with ZnO seed layers. It was revealed that the morphology, orientation, crystal, and optical quality of the ZnO nanorod arrays highly depend on the crystal quality of ZnO seed layers, which was confirmed by the characterizations of field-emission scanning electron microscopy, X-ray diffraction, transmission electron microscopy, and photoluminescence measurements. For ZnO seed layer with wurtzite structure, the ZnO nanorods grew exactly normal to the substrate with perfect wurtzite structure, strong near-band-edge emission, and neglectable deep-level emission. The nanorods synthesized on the polycrystalline ZnO seed layer presented random orientation, wide diameter, and weak deep-level emission. This article provides a C-free and Au-free method for large-scale synthesis of vertical-aligned ZnO nanorod arrays by controlling the crystal quality of the seed layer.</p>
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spelling doaj-art-dbc8df3545ae4ebfa4fc64217b2e42402025-08-19T22:16:49ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2008-01-0139309314Selective Growth of Vertical-aligned ZnO Nanorod Arrays on Si Substrate by Catalyst-free Thermal EvaporationJiang YWang HZhang ZPWang XNMo QWang YZhu JHWang HBYang FJ<p>Abstract</p><p>By thermal evaporation of pure ZnO powders, high-density vertical-aligned ZnO nanorod arrays with diameter ranged in 80&#8211;250 nm were successfully synthesized on Si substrates covered with ZnO seed layers. It was revealed that the morphology, orientation, crystal, and optical quality of the ZnO nanorod arrays highly depend on the crystal quality of ZnO seed layers, which was confirmed by the characterizations of field-emission scanning electron microscopy, X-ray diffraction, transmission electron microscopy, and photoluminescence measurements. For ZnO seed layer with wurtzite structure, the ZnO nanorods grew exactly normal to the substrate with perfect wurtzite structure, strong near-band-edge emission, and neglectable deep-level emission. The nanorods synthesized on the polycrystalline ZnO seed layer presented random orientation, wide diameter, and weak deep-level emission. This article provides a C-free and Au-free method for large-scale synthesis of vertical-aligned ZnO nanorod arrays by controlling the crystal quality of the seed layer.</p>http://dx.doi.org/10.1007/s11671-008-9156-yZnOThermal evaporationNanorod arraysSeed layerCatalyst-free
spellingShingle Jiang Y
Wang H
Zhang ZP
Wang XN
Mo Q
Wang Y
Zhu JH
Wang HB
Yang FJ
Selective Growth of Vertical-aligned ZnO Nanorod Arrays on Si Substrate by Catalyst-free Thermal Evaporation
ZnO
Thermal evaporation
Nanorod arrays
Seed layer
Catalyst-free
title Selective Growth of Vertical-aligned ZnO Nanorod Arrays on Si Substrate by Catalyst-free Thermal Evaporation
title_full Selective Growth of Vertical-aligned ZnO Nanorod Arrays on Si Substrate by Catalyst-free Thermal Evaporation
title_fullStr Selective Growth of Vertical-aligned ZnO Nanorod Arrays on Si Substrate by Catalyst-free Thermal Evaporation
title_full_unstemmed Selective Growth of Vertical-aligned ZnO Nanorod Arrays on Si Substrate by Catalyst-free Thermal Evaporation
title_short Selective Growth of Vertical-aligned ZnO Nanorod Arrays on Si Substrate by Catalyst-free Thermal Evaporation
title_sort selective growth of vertical aligned zno nanorod arrays on si substrate by catalyst free thermal evaporation
topic ZnO
Thermal evaporation
Nanorod arrays
Seed layer
Catalyst-free
url http://dx.doi.org/10.1007/s11671-008-9156-y
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