Improving sensitivity of XANES structural fit to the bridged metal–metal coordination

Hard X-ray absorption spectroscopy is a valuable in situ probe for non-destructive diagnostics of metal sites. The low-energy interval of a spectrum (XANES) contains information about the metal oxidation state, ligand type, symmetry and distances in the first coordination shell but shows almost no d...

Full description

Bibliographic Details
Published in:	Journal of Synchrotron Radiation
Main Authors:	S. V. Abrosimov, B. O. Protsenko, A. S. Mannaa, V. G. Vlasenko, S. A. Guda, I. A. Pankin, A. S. Burlov, Y. V. Koshchienko, A. A. Guda, A. V. Soldatov
Format:	Article
Language:	English
Published:	International Union of Crystallography 2024-05-01
Subjects:	xanes exafs machine learning vibrational spectroscopy radial basis functions improved hypercube sampling
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600577524002091

Similar Items

Dehydrogenation of Ethylene on Supported Palladium Nanoparticles: A Double View from Metal and Hydrocarbon Sides
by: Oleg A. Usoltsev, et al.
Published: (2020-08-01)

Synchrotron XANES and EXAFS evidences for Cr+6 and V+5 reduction within the oil shale ashes through mixing with natural additives and hydration process
by: Tayel El-Hasan, et al.
Published: (2021-04-01)

A Probabilistic Approach to Phosphorus Speciation of Soils Using P K-edge XANES Spectroscopy with Linear Combination Fitting
by: Jon Petter Gustafsson, et al.
Published: (2020-04-01)

X-Ray Absorption and Emission Spectroscopy in Pharmaceutical Applications: From Local Atomic Structure Elucidation to Protein-Metal Complex Analysis—A Review
by: Klaudia Wojtaszek, et al.
Published: (2025-10-01)

XANES spectroscopy for the clinician
by: Bazin, Dominique, et al.
Published: (2021-10-01)

Chemistry in Retrieved Ryugu Asteroid Samples Revealed by Non-Invasive X-ray Microanalyses: Pink-Beam Fluorescence CT and Tender-Energy Absorption Spectroscopy
by: Paul Northrup, et al.
Published: (2024-04-01)

Structural properties and thermal stability of cobalt- and chromium-doped α-MnO2 nanorods
by: Romana Cerc Korošec, et al.
Published: (2017-05-01)

Characterization of nanoparticle electrocatalysts using X-ray absorption spectroscopy
by: Nebojša Marinković, et al.
Published: (2015-12-01)

Residence Time Effects on Molybdenum Adsorption on Soils: Elucidation by Multi-Reaction Modeling and XANES Analysis
by: Wenguang Sun, et al.
Published: (2019-08-01)

Assessment of the Aerodynamic and Aeroelastic Performance of Long-Span Twin-Box Bridges Based upon Multidimensional Surrogate Models
by: Rameez Badhurshah, et al.
Published: (2024-06-01)

Iron Speciation in Different Saharan Dust Advections and Effect of the Procedural Blank on the Results From X-ray Absorption Spectroscopy and Selective Leaching Experiments
by: Chiara Petroselli, et al.
Published: (2020-07-01)

Fine structure characterization of zero-valent iron nanoparticles for decontamination of nitrites and nitrates in wastewater and groundwater
by: Kuen-Song Lin et al
Published: (2008-01-01)

Spectroscopic, Raman, EMPA, Micro-XRF and Micro-XANES Analyses of Sulphur Concentration and Oxidation State of Natural Apatite Crystals
by: Bo Xu, et al.
Published: (2020-11-01)

Ruthenium-based MOF catalysts for methanation of CO2 derivatives
by: Itziar Arnaiz, et al.
Published: (2025-07-01)

The Liquid Jet Endstation for Hard X-ray Scattering and Spectroscopy at the Linac Coherent Light Source
by: Cali Antolini, et al.
Published: (2024-05-01)

Area normalization of HERFD-XANES spectra
by: Luca Bugarin, et al.
Published: (2024-09-01)

Raman and XANES Spectroscopic Study of the Influence of Coordination Atomic and Molecular Environments in Biomimetic Composite Materials Integrated with Dental Tissue
by: Dmitry Goloshchapov, et al.
Published: (2021-11-01)

A Fine Analysis of Zn Species Structure and Distribution in Zn/ZSM-5 Catalysts by Linear Combination Fitting Analysis of XANES Spectra
by: Baichao Li, et al.
Published: (2024-01-01)

Characterization, X-ray Absorption Spectroscopic Analysis and Photocatalytic Activity of Co/Zn Co-Doped TiO<sub>2</sub> Nanoparticles Synthesized by One-Step Sonochemical Process
by: Wanichaya Mekprasart, et al.
Published: (2021-10-01)

Improved precision in As speciation analysis with HERFD-XANES at the As K-edge: the case of As speciation in mine waste. Corrigendum
by: Emily M. Saurette, et al.
Published: (2023-11-01)

RBF-Based Integrated Optimization Method of Structural and Turning Parameters for Low-Floor Axle Bridge
by: Xiaoke Li, et al.
Published: (2024-02-01)

Flux Growth and Characterization of Bulk InVO<sub>4</sub> Crystals
by: Olesia Voloshyna, et al.
Published: (2023-09-01)

Reversible Binding of Nitric Oxide in a Cu(II)-Containing Microporous Metal-Organic Framework
by: Konstantin A. Bikov, et al.
Published: (2025-07-01)

Friction-condition-dependent sulfide and sulfate evolution on dialkylpentasulfide tribofilm studied by XANES
by: Ganlin Zheng, et al.
Published: (2019-08-01)

Local Structure Analysis of Heavy Fermion Ce<sub>2</sub>Pt<sub>6</sub>Ga<sub>15</sub> with a Honeycomb Structure Using Extended X-Ray Absorption Fine Structure
by: Yuji Matsumoto, et al.
Published: (2025-04-01)

Coordenação local do Eu(III) em híbridos orgânicos/inorgânicos emissores de luz branca Eu(III) local coordination in white light emitters organic-inorganic hybrids
by: Luís D. Carlos, et al.
Published: (2001-08-01)

The state of palladium and copper on the surface of freshly prepared low temperature carbon monoxide oxidadation catalyst PdCl<sub>2</sub>-CuCl<sub>2/γ</sub>-Al<sub>2</sub>O<sub>3</sub>
by: D. N. Titov, et al.
Published: (2010-06-01)

In Situ XANES Studies on Extracted Copper from Scrap Cu/ITO Thin Film in an Ionic Liquid Containing Iodine/Iodide
by: Hsin-Liang Huang, et al.
Published: (2022-03-01)

Unravelling the role of iron and manganese oxides in colouring Late Antique glass by micro-XANES and micro-XRF spectroscopies
by: Francesca Gherardi, et al.
Published: (2024-01-01)

Coupling between γ-irradiation and synchrotron-radiation-based XAFS techniques for studying Mn-doped ZnO nanoparticles
by: N. G. Imam, et al.
Published: (2022-09-01)

Speciation of Phosphorus from Suspended Sediment Studied by Bulk and Micro-XANES
by: Qingxin Zhang, et al.
Published: (2020-08-01)

Operando Photo-Electrochemical Catalysts Synchrotron Studies
by: Mikhail A. Soldatov, et al.
Published: (2022-03-01)

Nanoscale Phase Separation and Lattice Complexity in VO2: The Metal–Insulator Transition Investigated by XANES via Auger Electron Yield at the Vanadium L23-Edge and Resonant Photoemission
by: Augusto Marcelli, et al.
Published: (2017-12-01)

Machine learning for efficient grazing-exit x-ray absorption near edge structure spectroscopy analysis: Bayesian optimization approach
by: Cafer Tufan Cakir, et al.
Published: (2024-01-01)

Tensile Microstrain Fluctuations in the BaPbO Units in Superconducting BaPb<sub>1−x</sub>Bi<sub>x</sub>O<sub>3</sub> by Scanning Dispersive Micro-XANES
by: Ruben Albertini, et al.
Published: (2023-07-01)

Integration of Fourier and Wavelet Transform for Adsorption Mechanism of Cesium Study Based on X-Ray Diffraction and Absorption Spectroscopy
by: Chi-Wen Hsieh, et al.
Published: (2025-01-01)

µ-X-ray fluorescence (XRF) and fluorine K-edge µ-X-ray absorption near-edge structure (XANES) spectroscopy for detection of PFAS distribution in the impacted concrete
by: Phong H.N. Vo, et al.
Published: (2024-11-01)

Margaritasita: Un mineral exclusivamente Chihuahuense
by: Fabián Guadalupe Faudoa Gómez, et al.
Published: (2025-01-01)

Parameter Sensitivity Analysis and Optimization of Electromagnetic Force Waves of Fractional Slot Surface-Mounted PM Motor With External Rotor
by: Jiakuan Xia, et al.
Published: (2023-01-01)

Alkali Uranyl Borates: Bond Length, Equatorial Coordination and 5f States
by: Myrtille O.J.Y. Hunault, et al.
Published: (2021-01-01)