Ceramic Materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> System, Obtained via Heat Treatment of Cement-Salt Stone Based on Powder Mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and NaH<sub>2</sub>PO<sub>4</sub>

Ceramic materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> system were obtained by firing cement-salt stone made from pastes based on powder mixtures including calcium citrate tetrahydrate Ca<sub>3</sub>(C<sub>6</sub>H<sub>5&...

وصف كامل

التفاصيل البيبلوغرافية
الحاوية / القاعدة:Ceramics
المؤلفون الرئيسيون: Otabek U. Toshev, Tatiana V. Safronova, Tatiana B. Shatalova, Yulia S. Lukina
التنسيق: مقال
اللغة:الإنجليزية
منشور في: MDPI AG 2023-02-01
الموضوعات:
monocalcium phosphate monohydrate
sodium dihydrogen phosphate
calcium citrate tetrahydrate
cement-salt stone
brushite
monetite
الوصول للمادة أونلاين:https://www.mdpi.com/2571-6131/6/1/36
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author Otabek U. Toshev
Tatiana V. Safronova
Tatiana B. Shatalova
Yulia S. Lukina
author_facet Otabek U. Toshev
Tatiana V. Safronova
Tatiana B. Shatalova
Yulia S. Lukina
author_sort Otabek U. Toshev
collection DOAJ
container_title Ceramics
description Ceramic materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> system were obtained by firing cement-salt stone made from pastes based on powder mixtures including calcium citrate tetrahydrate Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, monocalcium phosphate monohydrate (MCPM) Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and/or sodium dihydrogen phosphate NaH<sub>2</sub>PO<sub>4</sub>. The phase composition of the obtained samples of cement-salt stone after adding water, hardening and drying included brushite CaHPO<sub>4</sub>∙2H<sub>2</sub>O, monetite CaHPO<sub>4</sub> and also unreacted Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and/or NaH<sub>2</sub>PO<sub>4</sub>. The phase composition of ceramics in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> system obtained by firing cement-salt stone was formed due to thermal conversion of hydrated salt and heterophase reactions between components presented in samples during firing. The phase composition of ceramic samples based on powder mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O and Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O after firing at 900 °C included β-calcium pyrophosphate (CPP) β-Ca<sub>2</sub>P<sub>2</sub>O<sub>7</sub>. The phase composition of ceramic samples based on powder mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, and NaH<sub>2</sub>PO<sub>4</sub> after firing at 900 °C included β-sodium rhenanite β-CaNaPO<sub>4.</sub> The phase composition of ceramic samples based on powder mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and NaH<sub>2</sub>PO<sub>4</sub> after firing at 900 °C included β-Ca<sub>2</sub>P<sub>2</sub>O<sub>7</sub>, β-CaNaPO<sub>4,</sub> double calcium-sodium pyrophosphate Na<sub>2</sub>CaP<sub>2</sub>O<sub>7</sub>, and Na-substituted tricalcium phosphate Сa<sub>10</sub>Na(PO<sub>4</sub>)<sub>7</sub>. Obtained ceramic materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> system including biocompatible and biodegradable phases could be important for treatments of bone tissue defects by means of approaches of regenerative medicine.
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spelling doaj-art-e06a19d5b6cd492caef7ba5bcbcba3cb2025-08-19T22:48:47ZengMDPI AGCeramics2571-61312023-02-016160061810.3390/ceramics6010036Ceramic Materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> System, Obtained via Heat Treatment of Cement-Salt Stone Based on Powder Mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and NaH<sub>2</sub>PO<sub>4</sub>Otabek U. Toshev0Tatiana V. Safronova1Tatiana B. Shatalova2Yulia S. Lukina3Department of Materials Science, Lomonosov Moscow State University, Building, 73, Leninskie Gory, 1, Moscow 119991, RussiaDepartment of Materials Science, Lomonosov Moscow State University, Building, 73, Leninskie Gory, 1, Moscow 119991, RussiaDepartment of Materials Science, Lomonosov Moscow State University, Building, 73, Leninskie Gory, 1, Moscow 119991, RussiaNational Medical Research Center for Traumatology and Orthopedics Named after N.N. Priorov, Priorova, 10, Moscow 127299, RussiaCeramic materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> system were obtained by firing cement-salt stone made from pastes based on powder mixtures including calcium citrate tetrahydrate Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, monocalcium phosphate monohydrate (MCPM) Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and/or sodium dihydrogen phosphate NaH<sub>2</sub>PO<sub>4</sub>. The phase composition of the obtained samples of cement-salt stone after adding water, hardening and drying included brushite CaHPO<sub>4</sub>∙2H<sub>2</sub>O, monetite CaHPO<sub>4</sub> and also unreacted Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and/or NaH<sub>2</sub>PO<sub>4</sub>. The phase composition of ceramics in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> system obtained by firing cement-salt stone was formed due to thermal conversion of hydrated salt and heterophase reactions between components presented in samples during firing. The phase composition of ceramic samples based on powder mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O and Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O after firing at 900 °C included β-calcium pyrophosphate (CPP) β-Ca<sub>2</sub>P<sub>2</sub>O<sub>7</sub>. The phase composition of ceramic samples based on powder mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, and NaH<sub>2</sub>PO<sub>4</sub> after firing at 900 °C included β-sodium rhenanite β-CaNaPO<sub>4.</sub> The phase composition of ceramic samples based on powder mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and NaH<sub>2</sub>PO<sub>4</sub> after firing at 900 °C included β-Ca<sub>2</sub>P<sub>2</sub>O<sub>7</sub>, β-CaNaPO<sub>4,</sub> double calcium-sodium pyrophosphate Na<sub>2</sub>CaP<sub>2</sub>O<sub>7</sub>, and Na-substituted tricalcium phosphate Сa<sub>10</sub>Na(PO<sub>4</sub>)<sub>7</sub>. Obtained ceramic materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> system including biocompatible and biodegradable phases could be important for treatments of bone tissue defects by means of approaches of regenerative medicine.https://www.mdpi.com/2571-6131/6/1/36monocalcium phosphate monohydratesodium dihydrogen phosphatecalcium citrate tetrahydratecement-salt stonebrushitemonetite
spellingShingle Otabek U. Toshev
Tatiana V. Safronova
Tatiana B. Shatalova
Yulia S. Lukina
Ceramic Materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> System, Obtained via Heat Treatment of Cement-Salt Stone Based on Powder Mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and NaH<sub>2</sub>PO<sub>4</sub>
monocalcium phosphate monohydrate
sodium dihydrogen phosphate
calcium citrate tetrahydrate
cement-salt stone
brushite
monetite
title Ceramic Materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> System, Obtained via Heat Treatment of Cement-Salt Stone Based on Powder Mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and NaH<sub>2</sub>PO<sub>4</sub>
title_full Ceramic Materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> System, Obtained via Heat Treatment of Cement-Salt Stone Based on Powder Mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and NaH<sub>2</sub>PO<sub>4</sub>
title_fullStr Ceramic Materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> System, Obtained via Heat Treatment of Cement-Salt Stone Based on Powder Mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and NaH<sub>2</sub>PO<sub>4</sub>
title_full_unstemmed Ceramic Materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> System, Obtained via Heat Treatment of Cement-Salt Stone Based on Powder Mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and NaH<sub>2</sub>PO<sub>4</sub>
title_short Ceramic Materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> System, Obtained via Heat Treatment of Cement-Salt Stone Based on Powder Mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and NaH<sub>2</sub>PO<sub>4</sub>
title_sort ceramic materials in na sub 2 sub o cao p sub 2 sub o sub 5 sub system obtained via heat treatment of cement salt stone based on powder mixture of ca sub 3 sub c sub 6 sub h sub 5 sub o sub 7 sub sub 2 sub ∙4h sub 2 sub o ca h sub 2 sub po sub 4 sub sub 2 sub ∙h sub 2 sub o and nah sub 2 sub po sub 4 sub
topic monocalcium phosphate monohydrate
sodium dihydrogen phosphate
calcium citrate tetrahydrate
cement-salt stone
brushite
monetite
url https://www.mdpi.com/2571-6131/6/1/36
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