Effect of Acid and Alkaline Activation of Coconut Husk based Biochar for the Removal of Cadmium (II) ion from Aqueous Solution

In the environment, cadmium is toxic to plants, animals and micro-organisms, therefore its removal from industrial wastewater before discharging into recipient environment is necessary. The objective of this paper is to evaluate the effect of acid and alkaline activation of coconut husk based bioch...

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書誌詳細
出版年:Journal of Applied Sciences and Environmental Management
主要な著者: C. C. Njoku, D. C. Belonwu, M. O. Wegwu
フォーマット: 論文
言語:英語
出版事項: Joint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP) 2023-06-01
主題:
オンライン・アクセス:https://www.ajol.info/index.php/jasem/article/view/259449
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author C. C. Njoku
D. C. Belonwu
M. O. Wegwu
author_facet C. C. Njoku
D. C. Belonwu
M. O. Wegwu
author_sort C. C. Njoku
collection DOAJ
container_title Journal of Applied Sciences and Environmental Management
description In the environment, cadmium is toxic to plants, animals and micro-organisms, therefore its removal from industrial wastewater before discharging into recipient environment is necessary. The objective of this paper is to evaluate the effect of acid and alkaline activation of coconut husk based biochar for the removal of cadmium ion from aqueous solution. Data obtained reveal that coconut husk based Activated Carbon (A.C) exhibited high adsorption efficiency at a high pH of 10 with 99.8% and 99.6% of Cd (II) removal for alkaline and acid chemical activation respectively. The experimental kinetics data fit with the pseudo-second order model and the Freundlich isotherm model was found to be suitable for both type of chemical activation. Although, biochar activated with CaCl2 and H3PO4 showed good adsorption capacity of Cd (II) metal ion in aqueous solution but the Freundlich isotherm model applied in this study with (n) values of acid and alkaline A.C to be (1.12 and 0.72) respectively, depicts that Acid A.C has shown to have a better adsorption characteristics than alkaline coconut husk based activated carbon.
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spelling doaj-art-e446f1ecf03342d8b1079eaddda37c002025-08-19T22:57:16ZengJoint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP)Journal of Applied Sciences and Environmental Management2659-15022659-14992023-06-0127610.4314/jasem.v27i6.Effect of Acid and Alkaline Activation of Coconut Husk based Biochar for the Removal of Cadmium (II) ion from Aqueous SolutionC. C. NjokuD. C. BelonwuM. O. Wegwu In the environment, cadmium is toxic to plants, animals and micro-organisms, therefore its removal from industrial wastewater before discharging into recipient environment is necessary. The objective of this paper is to evaluate the effect of acid and alkaline activation of coconut husk based biochar for the removal of cadmium ion from aqueous solution. Data obtained reveal that coconut husk based Activated Carbon (A.C) exhibited high adsorption efficiency at a high pH of 10 with 99.8% and 99.6% of Cd (II) removal for alkaline and acid chemical activation respectively. The experimental kinetics data fit with the pseudo-second order model and the Freundlich isotherm model was found to be suitable for both type of chemical activation. Although, biochar activated with CaCl2 and H3PO4 showed good adsorption capacity of Cd (II) metal ion in aqueous solution but the Freundlich isotherm model applied in this study with (n) values of acid and alkaline A.C to be (1.12 and 0.72) respectively, depicts that Acid A.C has shown to have a better adsorption characteristics than alkaline coconut husk based activated carbon. https://www.ajol.info/index.php/jasem/article/view/259449Biochar; Coconut Husk; Activated Carbon; Cadmium
spellingShingle C. C. Njoku
D. C. Belonwu
M. O. Wegwu
Effect of Acid and Alkaline Activation of Coconut Husk based Biochar for the Removal of Cadmium (II) ion from Aqueous Solution
Biochar; Coconut Husk; Activated Carbon; Cadmium
title Effect of Acid and Alkaline Activation of Coconut Husk based Biochar for the Removal of Cadmium (II) ion from Aqueous Solution
title_full Effect of Acid and Alkaline Activation of Coconut Husk based Biochar for the Removal of Cadmium (II) ion from Aqueous Solution
title_fullStr Effect of Acid and Alkaline Activation of Coconut Husk based Biochar for the Removal of Cadmium (II) ion from Aqueous Solution
title_full_unstemmed Effect of Acid and Alkaline Activation of Coconut Husk based Biochar for the Removal of Cadmium (II) ion from Aqueous Solution
title_short Effect of Acid and Alkaline Activation of Coconut Husk based Biochar for the Removal of Cadmium (II) ion from Aqueous Solution
title_sort effect of acid and alkaline activation of coconut husk based biochar for the removal of cadmium ii ion from aqueous solution
topic Biochar; Coconut Husk; Activated Carbon; Cadmium
url https://www.ajol.info/index.php/jasem/article/view/259449
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AT dcbelonwu effectofacidandalkalineactivationofcoconuthuskbasedbiocharfortheremovalofcadmiumiiionfromaqueoussolution
AT mowegwu effectofacidandalkalineactivationofcoconuthuskbasedbiocharfortheremovalofcadmiumiiionfromaqueoussolution