Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate
The title compound {systematic name: bis[2-(1,3-dioxoisoindol-2-yl)ethyl]azanium chloride dihydrate}, C20H18N3O4+·Cl−·2H2O, is a phthalimide-protected polyamine that was synthesized by a previous method. It was characterized by ESI–MS, 1H NMR, and FT–IR. Crystals were grown from a solution of H2O an...
| الحاوية / القاعدة: | Acta Crystallographica Section E: Crystallographic Communications |
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| المؤلفون الرئيسيون: | , , , , |
| التنسيق: | مقال |
| اللغة: | الإنجليزية |
| منشور في: |
International Union of Crystallography
2023-06-01
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| الموضوعات: | |
| الوصول للمادة أونلاين: | http://scripts.iucr.org/cgi-bin/paper?S2056989023004565 |
| _version_ | 1850272081011277824 |
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| author | Barry S. Young Jamie L. Lee Milan Gembicky Jake Bailey Gary L. N. Smith |
| author_facet | Barry S. Young Jamie L. Lee Milan Gembicky Jake Bailey Gary L. N. Smith |
| author_sort | Barry S. Young |
| collection | DOAJ |
| container_title | Acta Crystallographica Section E: Crystallographic Communications |
| description | The title compound {systematic name: bis[2-(1,3-dioxoisoindol-2-yl)ethyl]azanium chloride dihydrate}, C20H18N3O4+·Cl−·2H2O, is a phthalimide-protected polyamine that was synthesized by a previous method. It was characterized by ESI–MS, 1H NMR, and FT–IR. Crystals were grown from a solution of H2O and 0.1 M HCl. The central nitrogen atom is protonated and forms hydrogen bonds with the chloride ion and a water molecule. The two phthalimide units make a dihedral angle of 22.07 (3)°. The crystal packing features a hydrogen-bond network, two-coordinated chloride, and off-set π–π stacking. |
| format | Article |
| id | doaj-art-e4916cd7d169417a8fc8ec9e1d524fd5 |
| institution | Directory of Open Access Journals |
| issn | 2056-9890 |
| language | English |
| publishDate | 2023-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| spelling | doaj-art-e4916cd7d169417a8fc8ec9e1d524fd52025-08-19T23:42:26ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902023-06-0179657557710.1107/S2056989023004565ex2070Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrateBarry S. Young0Jamie L. Lee1Milan Gembicky2Jake Bailey3Gary L. N. Smith4Department of Chemistry, San Diego Miramar College, San Diego, CA 92126, USADepartment of Chemistry, San Diego Miramar College, San Diego, CA 92126, USADepartment of Chemistry, University of California-San Diego, La Jolla, CA 92093, USADepartment of Chemistry, University of California-San Diego, La Jolla, CA 92093, USADepartment of Chemistry, San Diego Miramar College, San Diego, CA 92126, USAThe title compound {systematic name: bis[2-(1,3-dioxoisoindol-2-yl)ethyl]azanium chloride dihydrate}, C20H18N3O4+·Cl−·2H2O, is a phthalimide-protected polyamine that was synthesized by a previous method. It was characterized by ESI–MS, 1H NMR, and FT–IR. Crystals were grown from a solution of H2O and 0.1 M HCl. The central nitrogen atom is protonated and forms hydrogen bonds with the chloride ion and a water molecule. The two phthalimide units make a dihedral angle of 22.07 (3)°. The crystal packing features a hydrogen-bond network, two-coordinated chloride, and off-set π–π stacking.http://scripts.iucr.org/cgi-bin/paper?S2056989023004565crystal structurephthalimidesπ–π interactionstripodal ligand |
| spellingShingle | Barry S. Young Jamie L. Lee Milan Gembicky Jake Bailey Gary L. N. Smith Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate crystal structure phthalimides π–π interactions tripodal ligand |
| title | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_full | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_fullStr | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_full_unstemmed | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_short | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_sort | synthesis and crystal structure of bis 2 phthalimidoethyl ammonium chloride dihydrate |
| topic | crystal structure phthalimides π–π interactions tripodal ligand |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989023004565 |
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