The Recycling of Lithium from LiFePO₄ Batteries into Li₂CO₃ and Its Use as a CO₂ Absorber in Hydrogen Purification

• Published in: Clean Technologies
• Main Authors: Zoltán Köntös, Ádám Gyöngyössy
• Format: Article
• Language: English
• Published: MDPI AG 2024-11-01
• Subjects: recycling economy; lithium; LiFePO₄ battery; lithium carbonate; CO₂ capture; sustainable energy
• Online Access: https://www.mdpi.com/2571-8797/6/4/72

The growing adoption of lithium iron phosphate (LiFePO₄) batteries in electric vehicles (EVs) and renewable energy systems has intensified the need for sustainable management at the end of their life cycle. This study introduces an innovative method for recycling lithium from spent LiFePO₄ batteries and repurposing the recovered lithium carbonate (Li₂CO₃) as a carbon dioxide (CO₂) absorber. The recycling process involves dismantling battery packs, separating active materials, and chemically treating the cathode to extract lithium ions, which produces Li₂CO₃. The efficiency of lithium recovery is influenced by factors such as leaching temperature, acid concentration, and reaction time. Once recovered, Li₂CO₃ can be utilized for CO₂ capture in hydrogen purification processes, reacting with CO₂ to form lithium bicarbonate (LiHCO₃). This reaction, which is highly effective in aqueous solutions, can be applied in industrial settings to mitigate greenhouse gas emissions. The LiHCO₃ can then be thermally decomposed to regenerate Li₂CO₃, creating a cyclic and sustainable use of the material. This dual-purpose process not only addresses the environmental impact of LiFePO₄ battery disposal but also contributes to CO₂ reduction, aligning with global climate goals. Utilizing recycled Li₂CO₃ decreases the demand for virgin lithium extraction, supporting a circular economy. Furthermore, integrating Li₂CO₃-based CO₂ capture systems into existing industrial infrastructure provides a scalable and cost-effective solution for lowering carbon footprints while securing a continuous supply of lithium for future battery production. Future research should focus on optimizing lithium recovery methods, improving the efficiency of CO₂ capture, and exploring synergies with other waste management and carbon capture technologies. This comprehensive strategy underscores the potential of lithium recycling to address both resource conservation and environmental protection challenges.