Structural Consequences of Post-Synthetic Modification of Cu<sub>2</sub>P<sub>3</sub>I<sub>2</sub>

In an attempt to widen the family of Phosphorus Metal Halides (M<sub>x</sub>P<sub>y</sub>X<sub>z</sub>) and enable new applications, post-synthetic modifications to the M<sub>x</sub>P<sub>y</sub>X<sub>z,</sub> Cu<sub>2<...

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出版年:Micro
主要な著者: Gregory R. Schwenk, John T. Walters, Hai-Feng Ji
フォーマット: 論文
言語:英語
出版事項: MDPI AG 2023-03-01
主題:
オンライン・アクセス:https://www.mdpi.com/2673-8023/3/1/18
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author Gregory R. Schwenk
John T. Walters
Hai-Feng Ji
author_facet Gregory R. Schwenk
John T. Walters
Hai-Feng Ji
author_sort Gregory R. Schwenk
collection DOAJ
container_title Micro
description In an attempt to widen the family of Phosphorus Metal Halides (M<sub>x</sub>P<sub>y</sub>X<sub>z</sub>) and enable new applications, post-synthetic modifications to the M<sub>x</sub>P<sub>y</sub>X<sub>z,</sub> Cu<sub>2</sub>P<sub>3</sub>I<sub>2</sub> have been reported. While such a technique suggests access to an entirely new family of M<sub>x</sub>P<sub>y</sub>X<sub>z</sub>-based materials, we report, in this work, that the ion-exchange process seemingly influences important properties such as the crystallographic pattern and vibrational modes.
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spelling doaj-art-e89dfe97e8124a1d84e3417769cd042f2025-08-20T00:09:14ZengMDPI AGMicro2673-80232023-03-013125626310.3390/micro3010018Structural Consequences of Post-Synthetic Modification of Cu<sub>2</sub>P<sub>3</sub>I<sub>2</sub>Gregory R. Schwenk0John T. Walters1Hai-Feng Ji2Department of Chemistry, Drexel University, Philadelphia, PA 19104, USADepartment of Chemistry, Drexel University, Philadelphia, PA 19104, USADepartment of Chemistry, Drexel University, Philadelphia, PA 19104, USAIn an attempt to widen the family of Phosphorus Metal Halides (M<sub>x</sub>P<sub>y</sub>X<sub>z</sub>) and enable new applications, post-synthetic modifications to the M<sub>x</sub>P<sub>y</sub>X<sub>z,</sub> Cu<sub>2</sub>P<sub>3</sub>I<sub>2</sub> have been reported. While such a technique suggests access to an entirely new family of M<sub>x</sub>P<sub>y</sub>X<sub>z</sub>-based materials, we report, in this work, that the ion-exchange process seemingly influences important properties such as the crystallographic pattern and vibrational modes.https://www.mdpi.com/2673-8023/3/1/18phosphorusPhosphorus Metal Halideion-exchangeCu<sub>2</sub>P<sub>3</sub>I<sub>2</sub>Ag<sub>2</sub>P<sub>3</sub>I<sub>2</sub>powder X-ray diffraction
spellingShingle Gregory R. Schwenk
John T. Walters
Hai-Feng Ji
Structural Consequences of Post-Synthetic Modification of Cu<sub>2</sub>P<sub>3</sub>I<sub>2</sub>
phosphorus
Phosphorus Metal Halide
ion-exchange
Cu<sub>2</sub>P<sub>3</sub>I<sub>2</sub>
Ag<sub>2</sub>P<sub>3</sub>I<sub>2</sub>
powder X-ray diffraction
title Structural Consequences of Post-Synthetic Modification of Cu<sub>2</sub>P<sub>3</sub>I<sub>2</sub>
title_full Structural Consequences of Post-Synthetic Modification of Cu<sub>2</sub>P<sub>3</sub>I<sub>2</sub>
title_fullStr Structural Consequences of Post-Synthetic Modification of Cu<sub>2</sub>P<sub>3</sub>I<sub>2</sub>
title_full_unstemmed Structural Consequences of Post-Synthetic Modification of Cu<sub>2</sub>P<sub>3</sub>I<sub>2</sub>
title_short Structural Consequences of Post-Synthetic Modification of Cu<sub>2</sub>P<sub>3</sub>I<sub>2</sub>
title_sort structural consequences of post synthetic modification of cu sub 2 sub p sub 3 sub i sub 2 sub
topic phosphorus
Phosphorus Metal Halide
ion-exchange
Cu<sub>2</sub>P<sub>3</sub>I<sub>2</sub>
Ag<sub>2</sub>P<sub>3</sub>I<sub>2</sub>
powder X-ray diffraction
url https://www.mdpi.com/2673-8023/3/1/18
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