Valorization of Kraft Pulp and Paper Mill Slaker Grits and Biomass Fly Ash as Fillers in a Commercial Screed Mortar Formulation

Slaker grits (SG) and biomass fly ash (BFA), two waste streams generated in the pulp and paper industry, are commonly disposed of in landfills, a practice with a high economic and environmental burden. In this work, their individual valorization as fillers in a commercial screed mortar formulation w...

Full description

Bibliographic Details
Published in:Molecules
Main Authors: Marinélia N. Capela, Inês S. Vilarinho, Inês Vieira, Luís A. C. Tarelho, Maria P. Seabra, João A. Labrincha
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Subjects:
Online Access:https://www.mdpi.com/1420-3049/27/23/8613
_version_ 1850033456745021440
author Marinélia N. Capela
Inês S. Vilarinho
Inês Vieira
Luís A. C. Tarelho
Maria P. Seabra
João A. Labrincha
author_facet Marinélia N. Capela
Inês S. Vilarinho
Inês Vieira
Luís A. C. Tarelho
Maria P. Seabra
João A. Labrincha
author_sort Marinélia N. Capela
collection DOAJ
container_title Molecules
description Slaker grits (SG) and biomass fly ash (BFA), two waste streams generated in the pulp and paper industry, are commonly disposed of in landfills, a practice with a high economic and environmental burden. In this work, their individual valorization as fillers in a commercial screed mortar formulation was evaluated in order to achieve a more sustainable management practice. The waste streams were characterized in terms of true density, particle size and morphology, and chemical and mineralogical composition. The influence of their incorporation amount (5.0, 7.5, and 10.0 wt.% of the total solids) and pre-treatment (sieving and grinding) on the fresh (workability) and hardened state (density, water absorption by capillarity, and flexural and compressive strength) properties of the mortars were assessed. The results show that the addition of 10.0 wt.% of the SG after milling and sieving (<75 µm) and 7.5 wt.% of BFA in the as-received condition, or up to 10.0 wt.% after grinding and sieving (<63 µm), allowed for the production of mortar samples with properties within the recommended specifications and that were resistant to 25 consecutive freeze-thaw cycles. This waste valorization route could represent an economic benefit of up to 8.85 €/t<sub>mortar</sub> and 2.87 €/t<sub>mortar</sub> for mortar, and pulp and paper companies, respectively.
format Article
id doaj-art-e90b5976d8df43239642f6ed18bcc280
institution Directory of Open Access Journals
issn 1420-3049
language English
publishDate 2022-12-01
publisher MDPI AG
record_format Article
spelling doaj-art-e90b5976d8df43239642f6ed18bcc2802025-08-20T00:35:09ZengMDPI AGMolecules1420-30492022-12-012723861310.3390/molecules27238613Valorization of Kraft Pulp and Paper Mill Slaker Grits and Biomass Fly Ash as Fillers in a Commercial Screed Mortar FormulationMarinélia N. Capela0Inês S. Vilarinho1Inês Vieira2Luís A. C. Tarelho3Maria P. Seabra4João A. Labrincha5Department of Materials and Ceramic Engineering, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Materials and Ceramic Engineering, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Materials and Ceramic Engineering, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Environment and Planning, CESAM—Centre for Environmental and Marine Studies, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Materials and Ceramic Engineering, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Materials and Ceramic Engineering, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, PortugalSlaker grits (SG) and biomass fly ash (BFA), two waste streams generated in the pulp and paper industry, are commonly disposed of in landfills, a practice with a high economic and environmental burden. In this work, their individual valorization as fillers in a commercial screed mortar formulation was evaluated in order to achieve a more sustainable management practice. The waste streams were characterized in terms of true density, particle size and morphology, and chemical and mineralogical composition. The influence of their incorporation amount (5.0, 7.5, and 10.0 wt.% of the total solids) and pre-treatment (sieving and grinding) on the fresh (workability) and hardened state (density, water absorption by capillarity, and flexural and compressive strength) properties of the mortars were assessed. The results show that the addition of 10.0 wt.% of the SG after milling and sieving (<75 µm) and 7.5 wt.% of BFA in the as-received condition, or up to 10.0 wt.% after grinding and sieving (<63 µm), allowed for the production of mortar samples with properties within the recommended specifications and that were resistant to 25 consecutive freeze-thaw cycles. This waste valorization route could represent an economic benefit of up to 8.85 €/t<sub>mortar</sub> and 2.87 €/t<sub>mortar</sub> for mortar, and pulp and paper companies, respectively.https://www.mdpi.com/1420-3049/27/23/8613biomass fly ashlime slaker gritspre-treatmentscement mortarfillerfreeze-thaw resistance
spellingShingle Marinélia N. Capela
Inês S. Vilarinho
Inês Vieira
Luís A. C. Tarelho
Maria P. Seabra
João A. Labrincha
Valorization of Kraft Pulp and Paper Mill Slaker Grits and Biomass Fly Ash as Fillers in a Commercial Screed Mortar Formulation
biomass fly ash
lime slaker grits
pre-treatments
cement mortar
filler
freeze-thaw resistance
title Valorization of Kraft Pulp and Paper Mill Slaker Grits and Biomass Fly Ash as Fillers in a Commercial Screed Mortar Formulation
title_full Valorization of Kraft Pulp and Paper Mill Slaker Grits and Biomass Fly Ash as Fillers in a Commercial Screed Mortar Formulation
title_fullStr Valorization of Kraft Pulp and Paper Mill Slaker Grits and Biomass Fly Ash as Fillers in a Commercial Screed Mortar Formulation
title_full_unstemmed Valorization of Kraft Pulp and Paper Mill Slaker Grits and Biomass Fly Ash as Fillers in a Commercial Screed Mortar Formulation
title_short Valorization of Kraft Pulp and Paper Mill Slaker Grits and Biomass Fly Ash as Fillers in a Commercial Screed Mortar Formulation
title_sort valorization of kraft pulp and paper mill slaker grits and biomass fly ash as fillers in a commercial screed mortar formulation
topic biomass fly ash
lime slaker grits
pre-treatments
cement mortar
filler
freeze-thaw resistance
url https://www.mdpi.com/1420-3049/27/23/8613
work_keys_str_mv AT marineliancapela valorizationofkraftpulpandpapermillslakergritsandbiomassflyashasfillersinacommercialscreedmortarformulation
AT inessvilarinho valorizationofkraftpulpandpapermillslakergritsandbiomassflyashasfillersinacommercialscreedmortarformulation
AT inesvieira valorizationofkraftpulpandpapermillslakergritsandbiomassflyashasfillersinacommercialscreedmortarformulation
AT luisactarelho valorizationofkraftpulpandpapermillslakergritsandbiomassflyashasfillersinacommercialscreedmortarformulation
AT mariapseabra valorizationofkraftpulpandpapermillslakergritsandbiomassflyashasfillersinacommercialscreedmortarformulation
AT joaoalabrincha valorizationofkraftpulpandpapermillslakergritsandbiomassflyashasfillersinacommercialscreedmortarformulation