Effects of Graphite Addition on Structure and Properties of CrCuFeNiTiAl<sub>1</sub> High-Entropy Alloys

In this study, the CrCuFeNiTiAl<sub>1</sub> equiatomic alloy was used as a base, which was modified by adding graphite in proportions of 0.5, 1.0, 2.5, and 5.0 mol%. The samples were obtained by powder metallurgy and sintering at 1200 °C for 2 h in a furnace with a protective argon atmos...

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Bibliographic Details
Published in:Eng
Main Authors: Sergio Antonio García-Estrada, Ivanovich Estrada-Guel, Carlos Gamaliel Garay-Reyes, Cynthia Deisy Gómez-Esparza, Roberto Martínez-Sánchez, José Adalberto Castillo-Robles, José Amparo Rodríguez-García, Carlos Adrián Calles-Arriaga, Enrique Rocha-Rangel
Format: Article
Language:English
Published: MDPI AG 2025-05-01
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Online Access:https://www.mdpi.com/2673-4117/6/6/112
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Summary:In this study, the CrCuFeNiTiAl<sub>1</sub> equiatomic alloy was used as a base, which was modified by adding graphite in proportions of 0.5, 1.0, 2.5, and 5.0 mol%. The samples were obtained by powder metallurgy and sintering at 1200 °C for 2 h in a furnace with a protective argon atmosphere. Structural characterization was performed by XRD. A microstructural evaluation was conducted by SEM. The best mechanical microhardness and compressive strength results were obtained in the samples with the lowest amounts of graphite (238 μHV and 1000 MPa, respectively). The density values showed that samples with low amounts of graphite had better densification, lower porosity, and finer structural characteristics than those with graphite percentages higher than 1 mol%. The XRD studies determined the formation of a mixture of crystalline structures composed of FCC due to the presence of Cu, Ni, and Al metals; BCC due to Fe and Cr metals; and HCP due to Ti, and the formation of a Cr<sub>7</sub>C<sub>3</sub> compound. SEM analysis showed the formation of cracks and porosity due to the formation of carbides.
ISSN:2673-4117