| 总结: | The study examined the chemical structure of azo-based liquid crystalline compounds that were altered to form a branch of cyclotriphosphazene. Moreover, the research explored the interplay between their mesomorphic and dielectric properties. The structures of the compounds were defined by Fourier transform infrared spectroscopy, nuclear magnetic resonance spectroscopy, and CHN elemental analysis. Only intermediates <b>2a</b>–<b>e</b> and cyclotriphosphazene compounds <b>4d</b>–<b>e</b> were mesogenic with smectic A (SmA) and smectic C (SmC) phases, respectively. Intermediate <b>2d</b> and compound <b>4d</b> were used as representative samples to determine the type of liquid crystal, which was confirmed through X-ray diffraction (XRD). The calculated d/L ratios for both compounds were 1.69 and 0.76, respectively, indicating that d was approximately equal to L (d ≈ L ≈ 1). This finding suggests that the SmA and SmC phases observed under polarized optical microscope (POM) are arranged in a monolayer. For the dielectric study, only compounds <b>2d</b>–<b>e</b> and <b>4d</b>–<b>e</b> were proceeded and compared for dielectric characteristics testing. The dielectric constants and dielectric loss factors of these four compounds were measured over the frequency range of 100 Hz to 0.1 MHz at room temperature. The dielectric constant trend decreased with the increasing frequency. Meanwhile, the dielectric loss showed two types of trends. The first trend was identical to the dielectric constant trend, in which the dielectric loss decreased as the frequency increased. However, in the second trend, the dielectric loss began to rise with the increase in frequency and then began to fall gradually after reaching a certain peak. Meanwhile, compounds <b>4d</b> and <b>4e</b> had low dielectric constants and losses due to the effect of hexasubstituted cyclotriphosphazene that had been attached as a core.
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