Energy Transfer Catalysis Enabled 2,2,2‐Trifluoroethoxy‐Amination of Olefins

A thioxanthone‐catalyzed 2,2,2‐trifluoroethoxyamination of olefins is developed via the formation of the corresponding alkoxy and iminyl radicals using unprecedented, easily prepared, and bench‐stable oxime ethers as bifunctional reagents. To bypass possible side reactions (1,2‐Hydrogen Atom Transfe...

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發表在:	ChemistryEurope
Main Authors:	Floriane Doche, Thibault Gallavardin, Thomas Poisson, Tatiana Besset
格式:	Article
語言:	英语
出版:	Wiley-VCH 2025-07-01
主題:	alkoxy radical generation bifunctional reagents energy transfer photocatalysis 2,2,2‐trifluoroethoxyamination reactions
在線閱讀:	https://doi.org/10.1002/ceur.202500041