In Situ Catalytic Methanation of Real Steelworks Gases

The by-product gases from the blast furnace and converter of an integrated steelworks highly contribute to today’s global CO<sub>2</sub> emissions. Therefore, the steel industry is working on solutions to utilise these gases as a carbon source for product synthesis in order to reduce the...

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Bibliographic Details
Published in:Energies
Main Authors: Philipp Wolf-Zoellner, Ana Roza Medved, Markus Lehner, Nina Kieberger, Katharina Rechberger
Format: Article
Language:English
Published: MDPI AG 2021-12-01
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Online Access:https://www.mdpi.com/1996-1073/14/23/8131
Description
Summary:The by-product gases from the blast furnace and converter of an integrated steelworks highly contribute to today’s global CO<sub>2</sub> emissions. Therefore, the steel industry is working on solutions to utilise these gases as a carbon source for product synthesis in order to reduce the amount of CO<sub>2</sub> that is released into the environment. One possibility is the conversion of CO<sub>2</sub> and CO to synthetic natural gas through methanation. This process is currently extensively researched, as the synthetic natural gas can be directly utilised in the integrated steelworks again, substituting for natural gas. This work addresses the in situ methanation of real steelworks gases in a lab-scaled, three-stage reactor setup, whereby the by-product gases are directly bottled at an integrated steel plant during normal operation, and are not further treated, i.e., by a CO<sub>2</sub> separation step. Therefore, high shares of nitrogen are present in the feed gas for the methanation. Furthermore, due to the catalyst poisons present in the only pre-cleaned steelworks gases, an additional gas-cleaning step based on CuO-coated activated carbon is implemented to prevent an instant catalyst deactivation. Results show that, with the filter included, the steady state methanation of real blast furnace and converter gases can be performed without any noticeable deactivation in the catalyst performance.
ISSN:1996-1073