Crystal structure of catena-poly[[(3-tert-butylpyridine-κN)(4-tert-butylpyridine-κN)cadmium]-di-μ-thiocyanato-κ2N:S;κ2S:N]
In the crystal structure of the title compound, [Cd(NCS)2(C9H13N)2]n, the CdII cations are coordinated in a slightly distorted octahedral geometry by one 3-tert-butylpyridine ligand, one 4-tert-butylpyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thiocyanate ligands, all o...
| Published in: | Acta Crystallographica Section E |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2014-12-01
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| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814024647 |
| _version_ | 1852712832124059648 |
|---|---|
| author | Julia Werner Thorben Reinert Inke Jess Christian Näther |
| author_facet | Julia Werner Thorben Reinert Inke Jess Christian Näther |
| author_sort | Julia Werner |
| collection | DOAJ |
| container_title | Acta Crystallographica Section E |
| description | In the crystal structure of the title compound, [Cd(NCS)2(C9H13N)2]n, the CdII cations are coordinated in a slightly distorted octahedral geometry by one 3-tert-butylpyridine ligand, one 4-tert-butylpyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thiocyanate ligands, all of which are in general positions. These μ-1,3-bridging thiocyante anions bridge the CdII cations, forming chains that propagate parallel to the b axis. |
| format | Article |
| id | doaj-art-efeb628db0384a8aae5670c8f097d8ef |
| institution | Directory of Open Access Journals |
| issn | 1600-5368 |
| language | English |
| publishDate | 2014-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| spelling | doaj-art-efeb628db0384a8aae5670c8f097d8ef2025-08-19T21:15:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-12-017012m403m40410.1107/S1600536814024647pk2535Crystal structure of catena-poly[[(3-tert-butylpyridine-κN)(4-tert-butylpyridine-κN)cadmium]-di-μ-thiocyanato-κ2N:S;κ2S:N]Julia Werner0Thorben Reinert1Inke Jess2Christian Näther3Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, GermanyInstitut für Physikalische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 1, 24118 Kiel, GermanyInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, GermanyInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, GermanyIn the crystal structure of the title compound, [Cd(NCS)2(C9H13N)2]n, the CdII cations are coordinated in a slightly distorted octahedral geometry by one 3-tert-butylpyridine ligand, one 4-tert-butylpyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thiocyanate ligands, all of which are in general positions. These μ-1,3-bridging thiocyante anions bridge the CdII cations, forming chains that propagate parallel to the b axis.http://scripts.iucr.org/cgi-bin/paper?S1600536814024647crystal structurecadmium coordination polymerμ-1,3-thiocyanate anions |
| spellingShingle | Julia Werner Thorben Reinert Inke Jess Christian Näther Crystal structure of catena-poly[[(3-tert-butylpyridine-κN)(4-tert-butylpyridine-κN)cadmium]-di-μ-thiocyanato-κ2N:S;κ2S:N] crystal structure cadmium coordination polymer μ-1,3-thiocyanate anions |
| title | Crystal structure of catena-poly[[(3-tert-butylpyridine-κN)(4-tert-butylpyridine-κN)cadmium]-di-μ-thiocyanato-κ2N:S;κ2S:N] |
| title_full | Crystal structure of catena-poly[[(3-tert-butylpyridine-κN)(4-tert-butylpyridine-κN)cadmium]-di-μ-thiocyanato-κ2N:S;κ2S:N] |
| title_fullStr | Crystal structure of catena-poly[[(3-tert-butylpyridine-κN)(4-tert-butylpyridine-κN)cadmium]-di-μ-thiocyanato-κ2N:S;κ2S:N] |
| title_full_unstemmed | Crystal structure of catena-poly[[(3-tert-butylpyridine-κN)(4-tert-butylpyridine-κN)cadmium]-di-μ-thiocyanato-κ2N:S;κ2S:N] |
| title_short | Crystal structure of catena-poly[[(3-tert-butylpyridine-κN)(4-tert-butylpyridine-κN)cadmium]-di-μ-thiocyanato-κ2N:S;κ2S:N] |
| title_sort | crystal structure of catena poly 3 tert butylpyridine κn 4 tert butylpyridine κn cadmium di μ thiocyanato κ2n s κ2s n |
| topic | crystal structure cadmium coordination polymer μ-1,3-thiocyanate anions |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814024647 |
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