Preparation and characterization of fluorescent polysulfate based on fluorescein

Fluorescent polysulfate (PSE-FL) was prepared by condensation polymerization of bisphenol A (BA), propane-2,2-diyl bis(4,1-phenylene) bis(sulfurofluoridate) and fluorescein in high temperature solution, and its structure and fluorescence characteristics were investigated. The results showed that the...

وصف كامل

التفاصيل البيبلوغرافية
الحاوية / القاعدة:Hecheng xiangjiao gongye
المؤلف الرئيسي: LI Fu-chong1, LIU Wei2, CAO Wei2, LI Xu3, GUO Jun-hong1, CUI Jin-feng1, YANG Bao-ping1
التنسيق: مقال
اللغة:الصينية
منشور في: Editorial Office of China Synthetic Rubber Industry 2023-03-01
الموضوعات:
الوصول للمادة أونلاين:http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202302001
_version_ 1851936850949701632
author LI Fu-chong1, LIU Wei2, CAO Wei2, LI Xu3, GUO Jun-hong1, CUI Jin-feng1, YANG Bao-ping1
author_facet LI Fu-chong1, LIU Wei2, CAO Wei2, LI Xu3, GUO Jun-hong1, CUI Jin-feng1, YANG Bao-ping1
author_sort LI Fu-chong1, LIU Wei2, CAO Wei2, LI Xu3, GUO Jun-hong1, CUI Jin-feng1, YANG Bao-ping1
collection DOAJ
container_title Hecheng xiangjiao gongye
description Fluorescent polysulfate (PSE-FL) was prepared by condensation polymerization of bisphenol A (BA), propane-2,2-diyl bis(4,1-phenylene) bis(sulfurofluoridate) and fluorescein in high temperature solution, and its structure and fluorescence characteristics were investigated. The results showed that the number average molecular weight of the prepared PSE-FL was 33 413 g/mol, the weight average molecular weight was 55 043 g/mol and the molecular weight distribution index was 1.64. It was a typical amorphous polymer with decomposition temperature about 319 ℃ and a glass transition temperature about 128 ℃. The solid ultraviolet absorption test results showed that PSE-FL had the maximum absorption wavelength at 502 nm and the fluorescence emission spectrum showed that PSE-FL displayed the fluorescence emission wavelength at 554 nm.
format Article
id doaj-art-fd388bdc8d7a4bcda523391cfcd27464
institution Directory of Open Access Journals
issn 1000-1255
language zho
publishDate 2023-03-01
publisher Editorial Office of China Synthetic Rubber Industry
record_format Article
spelling doaj-art-fd388bdc8d7a4bcda523391cfcd274642025-08-19T21:52:06ZzhoEditorial Office of China Synthetic Rubber IndustryHecheng xiangjiao gongye1000-12552023-03-01462838710.19908/j.cnki.ISSN1000-1255.2023.02.008Preparation and characterization of fluorescent polysulfate based on fluoresceinLI Fu-chong1, LIU Wei2, CAO Wei2, LI Xu3, GUO Jun-hong1, CUI Jin-feng1, YANG Bao-ping10"1. School of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050, China; 2. Frontiers Science Center for Rare Isotope, Lanzhou University, Lanzhou 730000, China; 3. Lanzhou Petrochemical Research Center, Petrochemical Research Institute, PetroChina, Lanzhou 730060, China"Fluorescent polysulfate (PSE-FL) was prepared by condensation polymerization of bisphenol A (BA), propane-2,2-diyl bis(4,1-phenylene) bis(sulfurofluoridate) and fluorescein in high temperature solution, and its structure and fluorescence characteristics were investigated. The results showed that the number average molecular weight of the prepared PSE-FL was 33 413 g/mol, the weight average molecular weight was 55 043 g/mol and the molecular weight distribution index was 1.64. It was a typical amorphous polymer with decomposition temperature about 319 ℃ and a glass transition temperature about 128 ℃. The solid ultraviolet absorption test results showed that PSE-FL had the maximum absorption wavelength at 502 nm and the fluorescence emission spectrum showed that PSE-FL displayed the fluorescence emission wavelength at 554 nm. http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202302001polysulfatesulfur and fluorine exchange reactionfluoresceinclick chemistryfluorescent polysulfatefluorescence characteristics
spellingShingle LI Fu-chong1, LIU Wei2, CAO Wei2, LI Xu3, GUO Jun-hong1, CUI Jin-feng1, YANG Bao-ping1
Preparation and characterization of fluorescent polysulfate based on fluorescein
polysulfate
sulfur and fluorine exchange reaction
fluorescein
click chemistry
fluorescent polysulfate
fluorescence characteristics
title Preparation and characterization of fluorescent polysulfate based on fluorescein
title_full Preparation and characterization of fluorescent polysulfate based on fluorescein
title_fullStr Preparation and characterization of fluorescent polysulfate based on fluorescein
title_full_unstemmed Preparation and characterization of fluorescent polysulfate based on fluorescein
title_short Preparation and characterization of fluorescent polysulfate based on fluorescein
title_sort preparation and characterization of fluorescent polysulfate based on fluorescein
topic polysulfate
sulfur and fluorine exchange reaction
fluorescein
click chemistry
fluorescent polysulfate
fluorescence characteristics
url http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202302001
work_keys_str_mv AT lifuchong1liuwei2caowei2lixu3guojunhong1cuijinfeng1yangbaoping1 preparationandcharacterizationoffluorescentpolysulfatebasedonfluorescein