Functionalization of anthracene: A selective route to brominated 1,4-anthraquinones

Functionalization of anthracene: A selective route to brominated 1,4-anthraquinones

Efficient and stereoselective syntheses are described for the preparation of 2,3,9,10-tetrabromo-1,4-dimethoxy-1,2,3,4-tetrahydroanthracenes 7, 8 and the corresponding 1,4-diol 17 by silver ion-assisted solvolysis of hexabromotetrahydroanthracene 6. Base-promoted aromatization of 7 and 8 afforded sy...

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Bibliographic Details
Main Authors: Kiymet Berkil Akar, Osman Cakmak, Orhan Büyükgüngör, Ertan Sahin
Format: Article
Language:English
Published: Beilstein-Institut 2011-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
anthracene derivatives
anthracene-1,4-dione
aromatization
bromination
bromoanthracene
methoxyanthracene
silver-induced substitution
Online Access:https://doi.org/10.3762/bjoc.7.118

Internet

https://doi.org/10.3762/bjoc.7.118

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