[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate
In the title compound, [Ru3(C29H30P2)(C19H17PS)(CO)9]·0.25CH2Cl2, the atoms of the dichloromethane solvent molecule have a fractional site occupancy of 0.25; the dichloromethane molecule is disordered about an inversion centre. The bis(di-o-tolylphosphanyl)methane ligand bridges an Ru&a...
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International Union of Crystallography
2011-02-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681100081X |
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doaj-dbb4c5a9f4d941ab8deb02ba9bd017c12020-11-25T01:36:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672m195m19610.1107/S160053681100081X[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvateOmar bin ShawkatalyImthyaz Ahmed KhanH. A. Hafiz MalikChin Sing YeapHoong-Kun FunIn the title compound, [Ru3(C29H30P2)(C19H17PS)(CO)9]·0.25CH2Cl2, the atoms of the dichloromethane solvent molecule have a fractional site occupancy of 0.25; the dichloromethane molecule is disordered about an inversion centre. The bis(di-o-tolylphosphanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom; its S-bonded phenyl ring is disordered over two orientations in a 0.53 (4):0.47 (4) ratio. All the P atoms are equatorial with respect to the Ru3 triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings attached to each P atom of the diphenylphosphanyl ligand are 68.4 (2) and 71.5 (2)°. In the crystal, molecules are linked into [001] chains via intermolecular C—H...O hydrogen bonds. Weak intermolecular C—H...π interactions also occur. http://scripts.iucr.org/cgi-bin/paper?S160053681100081X |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Omar bin Shawkataly Imthyaz Ahmed Khan H. A. Hafiz Malik Chin Sing Yeap Hoong-Kun Fun |
spellingShingle |
Omar bin Shawkataly Imthyaz Ahmed Khan H. A. Hafiz Malik Chin Sing Yeap Hoong-Kun Fun [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate Acta Crystallographica Section E |
author_facet |
Omar bin Shawkataly Imthyaz Ahmed Khan H. A. Hafiz Malik Chin Sing Yeap Hoong-Kun Fun |
author_sort |
Omar bin Shawkataly |
title |
[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
title_short |
[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
title_full |
[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
title_fullStr |
[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
title_full_unstemmed |
[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
title_sort |
[μ-bis(di-o-tolylphosphanyl)methane-1:2κ2p:p′]nonacarbonyl-1κ3c,2κ3c,3κ3c-[diphenyl(phenylsulfanylmethyl)phosphane-3κp]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2011-02-01 |
description |
In the title compound, [Ru3(C29H30P2)(C19H17PS)(CO)9]·0.25CH2Cl2, the atoms of the dichloromethane solvent molecule have a fractional site occupancy of 0.25; the dichloromethane molecule is disordered about an inversion centre. The bis(di-o-tolylphosphanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom; its S-bonded phenyl ring is disordered over two orientations in a 0.53 (4):0.47 (4) ratio. All the P atoms are equatorial with respect to the Ru3 triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings attached to each P atom of the diphenylphosphanyl ligand are 68.4 (2) and 71.5 (2)°. In the crystal, molecules are linked into [001] chains via intermolecular C—H...O hydrogen bonds. Weak intermolecular C—H...π interactions also occur. |
url |
http://scripts.iucr.org/cgi-bin/paper?S160053681100081X |
work_keys_str_mv |
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