Oxidative additions of amides to an iridium(I) metal center
Carboxylic amides will add oxidatively via N-H activation to the complex [(COD)Ir(PMe3h]CI (where COD 1,5-cyclooctadiene) in organic solvents at 80°C to form stable iridium hydrides with the hydride arranged cis to nitrogen and trans to chloride. Acetamide will add to form the complex mer-(MeC(O)...
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| Format: | Others |
| Language: | en |
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Virginia Tech
2014
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| Online Access: | http://hdl.handle.net/10919/43458 http://scholar.lib.vt.edu/theses/available/etd-06232009-063527/ |