Manipulating tunnelling gateways in condensed phase isomerization

Abstract When a chemical reaction occurs via tunnelling, a simple mass‐dependence is expected, where substitution of atoms by heavier isotopes leads to a reduced reaction rate. However, as shown in a recent study of CO orientational isomerization at the NaCl(1 0 0) interface, the lightest isotopolog...

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Bibliographic Details

Published in:	Natural Sciences
Main Authors:	Arnab Choudhury, Shreya Sinha, David Harlander, Jessalyn DeVine, Alexander Kandratsenka, Peter Saalfrank, Dirk Schwarzer, Alec M. Wodtke
Format:	Article
Language:	English
Published:	Wiley-VCH 2023-07-01
Subjects:	astrochemistry gateway tunneling isomerization tunneling
Online Access:	https://doi.org/10.1002/ntls.20230006