Synthesis, crystal structure and Hirshfeld surface analysis of bis[2-amino-5-(ethylsulfanyl)-1,3,4-thiadiazol-3-ium] bis(perchlorato-κO)bis(picolinato-κ2N,O)copper(II)

In the title coordination complex, (C4H8N3S2)2[Cu(C6H4NO2)2(ClO4)2], the CuII center exhibits a distorted octahedral geometry with an equatorial plane formed by two bidentate picolinato ligands and axial coordination from two perchlorate anions, consistent with a Jahn–Teller distortion. The crystal...

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Bibliographic Details

Published in:	Acta Crystallographica Section E: Crystallographic Communications
Main Authors:	Gulnaz Khojabaeva, Batirbay Torambetov, Rajesh G. Gonnade, Zamira Uzakbergenova, Abdusamat Rasulov, Shakhnoza Kadirova
Format:	Article
Language:	English
Published:	International Union of Crystallography 2025-07-01
Subjects:	crystal structure copper(ii) complex picolinate ligand thiadiazole cation hirshfeld surface analysis hydrogen bonding supramolecular interactions jahn–teller distortion
Online Access:	https://journals.iucr.org/paper?S2056989025004992