Excited States Symmetry Breaking and In-Plane Polarization Cause Chiral Reversal in Diastereomers
In this work, we investigate the electronic transitions and chirality of three isomers of huge conjugated systems: asymmetric diastereomers (MMMM) and two symmetrical diastereomers (PMPM and PPMM). The physical mechanism of flipping has been studied theoretically. The new ribbon-shaped polycyclic ar...
| Published in: | Molecules |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2021-08-01
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| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/26/15/4680 |