Vibration-mediated long-wavelength photolysis of electronegative bonds beyond S0–S1 and S0–T1 transitions

Abstract Photolysis is an attractive method in organic synthesis to produce free radicals through direct bond cleavage. However, in this method, specific irradiation wavelengths of light have been considered indispensable for excitation through S0–Sn or S0–Tn transitions. Here we report the photoind...

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Bibliographic Details
Published in:Communications Chemistry
Main Authors: Antônio Junio Araujo Dias, Atsuya Muranaka, Masanobu Uchiyama, Ken Tanaka, Yuki Nagashima
Format: Article
Language:English
Published: Nature Portfolio 2024-06-01
Online Access:https://doi.org/10.1038/s42004-024-01208-0