Photoredox/HAT dual-catalyzed carboxylation of benzyl chlorides with CO2 using thiophenolate and formate as reductants

Carboxylation of benzyl chlorides with CO2 has been developed with photoredox/HAT dual-catalysis. The reaction could be conducted at room temperature with blue LED light source. Potassium formate (HCO2K) is used as a green reductant and a catalytic amount of sodium thiophenolate (PhSNa) is applied a...

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Bibliographic Details

Published in:	Tetrahedron Green Chem
Main Authors:	Zhengning Fan, Yaping Yi, Chanjuan Xi
Format:	Article
Language:	English
Published:	Elsevier 2023-12-01
Subjects:	Carbon dioxide: carboxylation: photoredox catalysis
Online Access:	http://www.sciencedirect.com/science/article/pii/S2773223123000274