Theoretical Studies on the Reaction Mechanism for the Cycloaddition of Zwitterionic π-Allenyl Palladium Species: Substrate-Controlled Isomerization

Zwitterionic π-allenyl palladium species are newly developed intermediates. A substrate-controlled step existed in the cycloaddition of zwitterionic π-allenyl palladium species with tropsulfimides or tropones. With the assistance of previously experimental studies, zwitterionic allenyl/propargyl pal...

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Bibliographic Details

Published in:	Molecules
Main Authors:	Yongjie Long, Jiahao Shen, Min Shi, Yin Wei
Format:	Article
Language:	English
Published:	MDPI AG 2024-12-01
Subjects:	mechanistic studies palladium catalyzed zwitterionic π-allenyl palladium species cycloaddition substrate-controlled reaction DFT calculation
Online Access:	https://www.mdpi.com/1420-3049/30/1/103