Synthetic Pathways Towards 1,3,4‐Tri‐ and Tetraphospholide Anions from White Phosphorus and Polyphosphides

Sodium polyphosphides NaxPn (Na[cyclo‐P5] and Na3P7), generated from white phosphorus and elemental sodium, react with phosphaalkynes R–C≡P (R = SiMe3, tBu, Ad, Mes) to give the respective sodium 2,5‐R‐1,3,4‐triphosphacyclopentadienide Na[1,3,4‐(cyclo‐(CR)2P3] either solely, or as a mixture with the...

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Bibliographic Details
Published in:ChemistryEurope
Main Authors: Moritz J. Ernst, Andrey Petrov, Manuela Weber, Christian Müller
Format: Article
Language:English
Published: Wiley-VCH 2026-04-01
Subjects:
cyclopentadienyl ligands
phosphaferrocenes
phosphorus cycles
white phosphorus
X‐ray diffraction
Online Access:https://doi.org/10.1002/ceur.70252

Internet

https://doi.org/10.1002/ceur.70252

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