Palladium‐Catalyzed Gem‐Diborylalkylation of Silyl Enol Ethers and N‐Vinylacetamide via Diboryl Carbon‐Centered Radicals

Abstract Herein, a palladium‐catalyzed coupling of gem‐iododiborylalkanes with electron‐rich olefins to access β,β‐diboryl ketones and aldehydes under mild conditions is reported. This method exhibits broad substrate scope and excellent functional group tolerance. Mechanistic studies support a disti...

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Bibliographic Details

Published in:	Advanced Science
Main Authors:	Xiao‐Yu Xie, Yi Wei, Xin‐Yi Chen, Ming Li, Kai Hong
Format:	Article
Language:	English
Published:	Wiley 2025-10-01
Subjects:	iododiboron organoboron palladium catalysis silyl enol ether synthetic methods
Online Access:	https://doi.org/10.1002/advs.202508566