A comparison of hydrogen abstraction reaction between allyl-type monomers with thioxanthone-based photoinitiators without amine synergists

The photodriven radical-mediated [3 + 2] cyclization reaction was found to yield polymers efficiently without being hindered by degradative chain transfer. The first reaction is a hydrogen abstraction process in which one hydrogen atom migrates from the α-methylene group of an allyl monomer to the t...

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Bibliographic Details

Published in:	Frontiers in Chemistry
Main Authors:	Xiaotian Zhao, Wen Xu, Xi Chen, Shibo Lin, Xuanhao Li, Lihui He, Xu Liao, Guodong Ye
Format:	Article
Language:	English
Published:	Frontiers Media S.A. 2022-09-01
Subjects:	allyl ether allyl thioxanthone density functional theory hydrogen abstraction transition state
Online Access:	https://www.frontiersin.org/articles/10.3389/fchem.2022.967836/full