An Overlooked Supramolecular Synthon in Multicomponent Trimethylglycine Crystals: Moderate Hydrogen Bonding Between Carboxylate and H-N Groups of Guanidine Species

Three novel multicomponent crystals of trimethylglycine with 2-cyanoguanidine, guanidinium and aminoguanidinium chlorides are synthesized and structurally characterized. All three crystal packings are based on the supramolecular synthon formed by two N–H groups of the guanidine species and carboxyla...

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Bibliographic Details

Published in:	Crystals
Main Authors:	Andrei V. Churakov, Alexander G. Medvedev, Nikita E. Frolov, Mikhail V. Vener
Format:	Article
Language:	English
Published:	MDPI AG 2024-11-01
Subjects:	2-cyanoguanidine guanidinium cation aminoguanidinium cation N,N,N-trimethyl-glycine periodic (solid-state) DFT computations enthalpy of intermolecular hydrogen bonds
Online Access:	https://www.mdpi.com/2073-4352/14/12/1050