Coupling Pyrazine to Dithiocarbonates for Molybdopterin Model Ligands—Indispensable Tin

Several synthetic cross-coupling procedures were (re-)evaluated for the tethering of pyrazine to dithiocarbonates. The resultant species constitute pro-ligands and can be converted by removal of the C=O moiety into ene-dithiolate ligand systems that model molybdopterin. The coupling of 2-iodopyrazin...

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書誌詳細

出版年:	Inorganics
主要な著者:	Siva Sankar Murthy Bandaru, Claudia Schindler, Felix Wenzek, Carola Schulzke
フォーマット:	論文
言語:	英語
出版事項:	MDPI AG 2023-04-01
主題:	Stille reaction stannylation copper(I)-thiophene-2-carboxylate 4-(pyrazin-2-yl)-1,3-dithiol-2-one ligand systems acetalization
オンライン･アクセス:	https://www.mdpi.com/2304-6740/11/5/188