Cluster Compounds with Oxidised, Hexanuclear [Nb6Cli12Ia6]n− Anions (n=2 or 3)

Abstract Four mixed‐halide cluster salts with chloride‐iodide‐supported octahedral Nb6 metal atoms cores were prepared and investigated. The cluster anions have the formula [Nb6Cli12Ia6]n− with Cl occupying the inner ligand sites and I the outer one. They are one‐ or two‐electron‐oxidized (n=2 or 3)...

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Published in:	ChemistryOpen
Main Authors:	M.Sc. Florian Schröder, Prof. Dr. Martin Köckerling
Format:	Article
Language:	English
Published:	Wiley-VCH 2022-06-01
Subjects:	cluster compounds halide niobium redox chemistry structure elucidation
Online Access:	https://doi.org/10.1002/open.202200063