Selective C‐7 Functionalization of Phenanthridines by Microwave‐Assisted Claisen Rearrangements of 8‐Allyloxyphenanthridines

Abstract Carbon‐carbon bond formation in the phenanthridine 7‐position was achieved by microwave‐assisted Claisen rearrangement of 8‐allyloxyphenanthridines. The reactions took place with excellent regioselectivity and high chemical yields. If the 7‐position was substituted, rearrangement to C‐9 too...

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Bibliographic Details
Published in:ChemistryOpen
Main Authors: Mathias Ryslett Lepsøe, Aleksander Granum Dalevold, Prof. Dr. Lise‐Lotte Gundersen
Format: Article
Language:English
Published: Wiley-VCH 2023-07-01
Subjects:
Claisen rearrangement
DFT calculations
microwave chemistry
nitrogen heterocycles
phenanthridines
Online Access:https://doi.org/10.1002/open.202300095

Internet

https://doi.org/10.1002/open.202300095

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