A robust ultra-microporous cationic aluminum-based metal-organic framework with a flexible tetra-carboxylate linker

Abstract Al-based cationic metal-organic frameworks (MOFs) are uncommon. Here, we report a cationic Al-MOF, MIP-213(Al) ([Al18(μ 2-OH)24(OH2)12(mdip)6]6Cl·6H2O) constructed from flexible tetra-carboxylate ligand (5,5'-Methylenediisophthalic acid; H4mdip). Its crystal structure was determined by...

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Bibliographic Details

Published in:	Communications Chemistry
Main Authors:	Shyamapada Nandi, Asma Mansouri, Iurii Dovgaliuk, Philippe Boullay, Gilles Patriarche, Ieuan Cornu, Pierre Florian, Georges Mouchaham, Christian Serre
Format:	Article
Language:	English
Published:	Nature Portfolio 2023-07-01
Online Access:	https://doi.org/10.1038/s42004-023-00938-x