Mechanisms of Sulfoxidation and Epoxidation Mediated by Iron(III)-Iodosylbenzene Adduct: Electron-Transfer vs. Oxygen-Transfer Mechanism

The mechanisms of sulfoxidation and epoxidation mediated by previously synthesized and characterized iron(III)-iodosylbenzene adduct, Fe<sup>III</sup>(OIPh) were investigated using para-substituted thioanisole and styrene derivatives as model substrates. Based on detailed kinetic reactio...

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Bibliographic Details
Published in:Molecules
Main Authors: Patrik Török, Dóra Lakk-Bogáth, József Kaizer
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Subjects:
non-heme models
iron(III)-iodosylarene complex
sulfoxidation
epoxidation
O-atom transfer
kinetics
Online Access:https://www.mdpi.com/1420-3049/28/12/4745

Internet

https://www.mdpi.com/1420-3049/28/12/4745

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